View More View Less
  • 1 Laboratoire de Thermodynamique et Energétique des Fluides Complexes, Université de Pau et de Pays de l'Adour, Avenue de l'université, 64013, Pau, France
Restricted access

Abstract

Single adsorption isotherms and differential enthalpies of adsorption of nitrogen were measured on a microporous-activated carbon at various temperatures. A new way for calculating the differential enthalpies of adsorption is presented, and the results obtained were compared to those obtained by the isosteric method derived from the equilibrium data using the Clausius–Clapeyron equation. The measurements were made thanks to a coupled thermostated calorimetric–manometric apparatus which can be operated for pressures up to 2.5 MPa and temperatures from 303 to 423 K. This article provides experimental data which can be used for the adjustment of interaction potential in computational simulations for supercritical adsorption.

  • 1. Gibbs, JW 1877 Collected works Longmans Green and Co. New York.

  • 2. Rouquerol, F, Rouquerol, J, Sing, K 1999 Adsorption by powders and porous solids: principles, methodology and applications Academic Press London.

    • Search Google Scholar
    • Export Citation
  • 3. Dabrowsko, A 2001 Adsorption from theory to practice. Adv Colloid Interface Sci 93:135224 .

  • 4. Al-Muhtaseb, SA, Abu Al-Rub, FA, Al Zarooni, M 2007 Adsorption equilibria of nitrogen, methane, and ethane on bdh-activated carbon. J Chem Eng Data 52:6065 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Dreisbach, F, Staudt, R, Keller, JU 1999 High pressure adsorption data of methane, nitrogen, carbon dioxide and their binary and ternary mixtures on activated carbon. Adsorption 5:215227 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Sudibandriyo, M, Pan, Z, Fitzgerald, JE RL Robinson Jr Gasem, KAM 2003 Adsorption of methane, nitrogen, carbon dioxide, and their binary mixtures on dry activated carbon at 318.2 K and pressures up to 13.6 MPa. Langmuir 19:53235331 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Staudt, R, Herbst, A, Beutekamp, S, Harting, P 2005 Adsorption of pure gases and mixtures on porous solids up to high pressures. Adsorption 11:379384 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Cavenati, S, Grande, CA, Rodrigues, AE 2004 Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13X at high pressures. J Chem Eng Data 49:10951101 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Himeno, S, Komatsu, T, Fujita, S 2005 High-pressure adsorption equilibria of methane and carbon dioxide on several activated carbons. J Chem Eng Data 50:369376 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Pini, R, Ottiger, S, Burlini, L, Storti, G, Mazzotti, M 2010 Sorption of carbon dioxide, methane and nitrogen in dry coals at high pressure and moderate temperature. Int J Greenh Gas Control 4:90101 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Belmabkhout, Y, Frère, M G De Weireld 2004 High-pressure adsorption measurements. A comparative study of the volumetric and gravimetric methods. Meas Sci Technol 15:848858 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Gensterblum, Y P Van Hemert Billemont, P, Busch, A, Charriére, D, Li, D, Krooss, BM G de Weireld Prinz, D, Wolf, K-HAA 2009 European inter-laboratory comparison of high pressure CO2 sorption isotherms. I. Activated carbon. Carbon 47:29582969 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Berlier, K, Frère, M 1996 Adsorption of CO2 on activated carbon: simultaneous determination of integral heat and isotherm of adsorption. J Chem Eng Data 41:11441148 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Berlier, K, Frère, M 1997 Adsorption of CO2 on microporous materials. 1. On activated carbon and silica gel. J Chem Eng Data 42:533537 .

  • 15. Sun, Y, Liu, C, Wei, S, Zhou, Y, Zhou, L 2009 Principles of methane adsorption and natural gas storage. Adsorption 15:133137 .

  • 16. Bazan, RE, Bastos-Neto, M, Moeller, A, Dreisbach, F, Staudt, R 2011 Adsorption equilibria of O2, Ar, Kr and Xe on activated carbon and zeolites: single component and mixture data. Adsorption 17:371383 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Barbosa MN , Araujo AS, Galvao LPFC, Silva EFB, Santos AGD, Luz GE Jr, Fernandes VJ, Jr. Carbon dioxide adsorption over DIPA functionalized MCM-41 and SBA-15 molecular sieves. J Therm Anal Calorim. 2011. doi: .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Denoyel, R, Beurroies, I, Vincent, D 2002 Microcalorimetric methods for studying vapour adsorption and wetting of powders. J Therm Anal Calorim 70:438492 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. wadso, I, Wadso, L 1997 A second generation twin double microcalorimeter measurements of sorption isotherms, heats of sorption and sorption kinetics. J Therm Anal 49:10451052 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Zimmerman, W, Keller, JU 2003 A new calorimeter for simultaneous measurement of isotherms and heats of adsorption. Thermochim Acta 405:3141 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21. Garcia-Cuello, V, Moreno-Pirajan, JC, Giraldo-Gutiérrez, L, Sapag, K, Zgrablich, G 2009 A new calorimeter of adsorption for the determination of differential enthalpies. Microporous Mesoporous Mater 120:239245 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Llewellyn, PL, Maurin, G 2005 Gas adsorption microcalorimetry and modeling to characterize zeolites and related materials. C.R. Chimie 8:283302 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23. Ferreira, AFP, Mittelmeijer-Hazeleger, MC, Bliek, A 2006 Adsorption and differential heats of adsorption of normal and iso-butane on zeolite MFI. Microporous Mesoporous Mater 91:4752 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Demir H , Mobedi M, Ulku S. Microcalorimetric investigation of water vapor adsorption on silica gel. J Therm Anal Calorim. 2001. doi: .

  • 25. Bulanek R , Frolich K, Frydova E, Cicmanec P. Study of adsorption sites heterogeneity in zeolites by means of coupled microcalorimetry with volumetry. J Therm Anal Calorim. 2010. doi: .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 26. Horvath, G, Kawazoe, K 1983 Method for the calculation of effective pore-size distribution in molecular-sieve carbon. J Chem Eng Jpn 16:470475 .

  • 27. Hurly JJ , Schmidt JW, Boyes SJ, Moldover MR. Virial equation of state of helium, xenon, and helium-xenon mixtures from speed of sound and burnett PρT measurement. Int J Thermophys 1997; 18 (3).

    • Search Google Scholar
    • Export Citation
  • 28. Bessières D , Lafitte Th, Daridon J-L, Randzio SL. High pressure thermal expansion of gases: measurements and calibration. Thermochim Acta 2005;428: 2530.

    • Search Google Scholar
    • Export Citation
  • 29. Randzio, SL, Grolier, J-PE, Quint, JR 1994 An isothermal scanning calorimeter controlled by linear pressure variations from 0.1 to 400 MPa calibration and comparison with the piezothermal technique. Rev Sci Instrum 65:960965 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30. Gravelle, PC 1978 Methods for the determination of heats of adsorption. J Therm Anal 14:5377 .

  • 31. Floess, JK, Kim, HH, Edens, G, Oleksy, SA, Kwak, J 1992 Surface area and heat of adsorption measurements of a microporous carbon. Carbon 30:10251032 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 32. Van Dongen RH , Broekho JCP. The isosteric heat of adsorption on homogeneous and patchwise heterogeneous surface. Surf Sci. 1969; 18.

    • Search Google Scholar
    • Export Citation
  • 33. Rothstein, DP, Bao-Gang, WU, Victor Lee, T, Madey, R 1985 Adsorption isotherms and isosteric heats of adsorption for ethane, propane, and n-butane on polystyrene. J Colloid Interface Sci 106:399409 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 34. Llewellyn, PL, Coulomb, J-P, Grillet, Y, Patarin, J, Lauter, H, Reichert, H, Rouquerol, J 1993 Adsorption by MFI-type zeolites examined by isothermal microcalorimetry and neutron-diffraction. 1. Argon, Krypton, and methane. Langmuir 9 7 18461851 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 35. Sircar, S 2001 Measurement of Gibbsian surface excess. AIChE J 47:11691176 .

  • 36. Cao, DV, Sircar, S 2001 Heat of adsorption of pure sulfur hexafluoride on micro-mesoporous adsorbents. Adsorption 7:7380 .

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2021 0 0 0
May 2021 2 1 0
Jun 2021 0 0 0
Jul 2021 0 0 0
Aug 2021 2 0 0
Sep 2021 0 0 0
Oct 2021 0 0 0