Geopolymers
Inorganic polymeric new materials
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V. A. Logvinenko
V. A. Logvinenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Ac. Lavrentiev Ave. 3, Novosibirsk-90, Russia, 630090
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M. P. Yutkin
M. P. Yutkin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Ac. Lavrentiev Ave. 3, Novosibirsk-90, Russia, 630090
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M. S. Zavakhina
M. S. Zavakhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Ac. Lavrentiev Ave. 3, Novosibirsk-90, Russia, 630090
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V. P. Fedin
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Ac. Lavrentiev Ave. 3, Novosibirsk-90, Russia, 630090
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Abstract
Inclusion compounds based on metal–organic frameworks (MOFs) have promising practical application in gas storage, separation and fine purification of substances, as well as in catalysis. MOFs are crystalline compounds consisting of metal ions coordinated by bridging organic ligands that form porous structures. The kinetics of the thermal decomposition of the frameworks themselves, namely [Co2(camph)2bpy] and [Co2(asp)2bpy], was investigated (camph and asp are the anions of camphoric and aspartic acids, bpy is the organic amine, 4,4′-bipyridyl). The empty coordination polymer framework based on metal camphorates was thermally (kinetically) less stable than the polymer framework based on metal aspartate. A high kinetic stability of frameworks with aspartic complexes during heating was due to the entropic factor rather than the enthalpic one.
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1. Zielenkiewicz, W, Kozbiał, M, Golankiewicz, B, Poznanski, J 2010 Enhancement of aqueous solubility of tricyclic acyclovir derivatives by their complexation with hydroxypropyl-b- cyclodextrin. J Therm Anal Calorim 101:555–560 .
-
2. Zielenkiewicz, W, Terekhova, IV, Kozbiał, M, Kumeev, RS 2010 Thermodynamic study on inclusion complex formation of riboflavin with hydroxypropyl-b-cyclodextrin in water. J Therm Anal Calorim 101:595–600 .
-
3. Serafini, MR, Menezes, PP, Costa, LP, Lima, CM LJ Quintans Jr Cardoso, JC, Matos, JR, Soares-Sobrinho, JL S Grangeiro Jr Nunes, PS, Bonjadim, LR, Araujo, AAS 2011 Interaction of p-cymene with b-cyclodextrin. J Therm Anal Calorim.
-
4. Dybtsev, DN, Yutkin, MP, Peresypkina, EV, Virovets, AV, Serre, C, Ferey, G, Fedin, VP 2007 Isoreticular homochiral porous metal–organic structures with tunable pore sizes. Inorg Chem 46:6843–6845 .
-
5. Dybtsev, DN, Yutkin, MP, Samsonenko, DG, Fedin, VP, Nuzhdin, AL, Bezrukov, AA, Bryliakov, KP, Talsi, EP, Belosludov, RV, Mizuseki, H, Kawazoe, Y, Subbotin, OS, Belosludov, VR 2010 Modular homochiral porous coordination polymers: rational design, enantioselective guest exchange sorption and ab initio calculations of host–guest interactions. Chem Eur J 10:348–356.
-
6. Netzsch Thermokinetics. http://www.netzsch-thermal-analysis.com/us/thermokinetics-workshop.
-
7. Kissinger, HE 1957 Reaction kinetics in differential thermal analysis. Anal Chem 29:1702–1706 .
-
8. Friedman, HL 1963 Kinetics of thermal degradation of char-forming plastics from thermogravimetry. J Polym Sci 6:183–195.
-
9. Ozawa, T 1965 A new method of analyzing thermogravimetric data. Bull Chem Soc Japan 38:1881–1886 .
-
10. Ozawa, T 1992 Estimation of activation energy by isoconversion methods. Thermochim Acta 203:159–165 .
-
11. Flynn, JH, Wall, LA 1966 General treatment of the thermogravimetry of polymers. J Res Nat Bur Stand 70:478–523.
-
12. Opfermann, J, Kaisersberger, E 1992 An advantageous variant of the Ozawa–Flynn–Wall analysis. Thermochim Acta 203:167–175 .
-
13. Opfermann, JR, Kaisersberger, E, Flammersheim, HJ 2002 Model-free analysis of thermo-analytical data-advantages and limitations. Thermochim Acta 391:119–127 .
-
14. Vyazovkin, S 2006 Model-free kinetics: staying free of multiplying entities without necessity. J Therm Anal Calorim 83:45–51 .
-
15. Simon, P 2005 Single-step kinetics approximation employing nonarrhenius temperature functions. J Therm Anal Calorim 79:703–708 .
-
16. Simon, P 2007 The single-step approximation: attributes, strong and weak sides. J Therm Anal Calorim 88:709–715 .
-
17. Vyazovkin, S, Burnham, AK, Criado, JM, Luis, A, Perez-Maqueda, LA, Popescu, C, Sbirrazzuoli, N 2011 ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data. Thermochim Acta 520:1–19 .
-
18. Logvinenko, V 1999 Stability and reactivity of coordination and inclusion compounds in the reversible processes of thermal dissociation. Thermochim Acta 340 1 293–299 .
-
19. Logvinenko, V 2000 Solid state coordination chemistry. The quantitative thermoanalytical study of thermal dissociation reactions. J Therm Anal Calorim 60:9–15 .
-
20. Logvinenko, V 2010 Stability of supramolecular compounds under heating. Thermodynamic and kinetic aspects. J Therm Anal Calorim 101:577–583 .
-
21. Logvinenko, V, Dybtsev, D, Fedin, V, Drebushchak, V, Yutkin, M 2010 The stability of inclusion compounds under heating Part 2 Inclusion compounds of layered zinc camphorate, linked by linear N-donor ligands. J Therm Anal Calorim 100:183–189 .
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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