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  • 1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Ac. Lavrentiev Ave. 3, Novosibirsk-90, Russia, 630090
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Abstract

Inclusion compounds based on metal–organic frameworks (MOFs) have promising practical application in gas storage, separation and fine purification of substances, as well as in catalysis. MOFs are crystalline compounds consisting of metal ions coordinated by bridging organic ligands that form porous structures. The kinetics of the thermal decomposition of the frameworks themselves, namely [Co2(camph)2bpy] and [Co2(asp)2bpy], was investigated (camph and asp are the anions of camphoric and aspartic acids, bpy is the organic amine, 4,4′-bipyridyl). The empty coordination polymer framework based on metal camphorates was thermally (kinetically) less stable than the polymer framework based on metal aspartate. A high kinetic stability of frameworks with aspartic complexes during heating was due to the entropic factor rather than the enthalpic one.

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Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)