View More View Less
  • 1 Department of Inorganic Chemistry, Faculty of Engineering and Economics, Wrocław University of Economics, Komandorska 118/120, 53-345, Wrocław, Poland
  • | 2 Faculty of Chemistry, University of Wrocław, ul. F. Joliot-Curie 14, 50-383, Wrocław, Poland
Restricted access

Abstract

The organic–inorganic coordination polymer of the general formula {[NiL][Co(NCS)4]}n (where L = 5,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been synthesized and characterized by IR, UV–Vis, DSC/TG, DTA/TG/MS methods. The magnetic behaviour of this complex has also been investigated within the temperature range 1.8–300 K. The IR spectrum indicates the presence of bridging M–NCS–M′ ligands. The absorption bands of UV–Vis spectrum confirm that the coordination environment of nickel(II) ions changes from square planar for [NiL](ClO4)2 to octahedral for {[NiL][Co(NCS)4]}n. The obtained compound is stable at room temperature, but within the range 246–282 °C decomposes in a three-stage process. The first step is associated with decomposition of the coordination polymer to the cationic [NiL]2+ and anionic [Co(NCS)4]2− units; the next two stages correspond to gradual decomposition of the macrocyclic ring. The value of molar magnetic susceptibility (χMT = 2.16 cm3 mol−1 K) indicates that the compound is paramagnetic.

  • 1. Cristóvão, B, Kłak, J, Miroslaw, B, Mazur, L 2011 Synthesis, crystal structures and magnetic characterization of heterodinuclear CuIIGdIII and CuIITbIII Schiff base complexes. Inorg Chim Acta 378:288296 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Mroziński, J, Kłak, J, Kruszyński, R 2008 Crystal structure and magnetic properties of the 1D bimetallic thiocyanate bridged compound: {(CuL1)[Co(NCS)4]}(L1 = N-rac-5,12-Me2-[14]-4,11-dieneN4). Polyhedron. 27:14011407 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Bieńko, A, Kłak, J, Mroziński, J, Kruszyński, R, Bieńko, DC, Boča, R 2008 Rhenium(IV)–copper(II) heterobimetallic complexes: synthesis, crystal structure and magnetic properties. Polyhedron. 27:24642470 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Wyrzykowski, D, Kruszyński, R, Kłak, J, Mroziński, J, Warnke, Z 2007 Synthesis and magnetic characteristics of new tetrachloroferrates(III) with 2-methylpyridinium, 3-methylpyridinium and 4-methylpyridinium cations: X-ray crystal structure of 4-methylpyridinium tetrachloroferrate(III). Inorg Chim Acta 360:33543360 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Mondal, N, Saha, MK, Mitra, S, Gramlich, V, Salah, M 2000 Synthesis, characterization and crystal structure of cyano-bridged dinuclear copper–iron. Polyhedron. 19:19351939 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Nemec, I, Herchel, R, Boča, R, Svoboda, I, Trávníček, Z, Dlháň, L, Matelková, K, Fuess, H 2011 Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates. Inorg Chim Acta 366:366372 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Karadağ, A, Şenocak, A, Önal, I, Yerli, Y, Şahin, E, Başaran, AC 2009 Preparation, structural, magnetic and thermal properties of two heterobimetallic cyano-bridged nickel(II)–copper(II)/platinum(II) coordination polymers. Inorg Chim Acta 362:22992304 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Shevchenko, DV, Petrusenko, SR, Kokozay, VN, Tomkiewicz, A, Kłak, J, Mroziński, J, Krasovska, MV, Shishkin, OV, Linert, W 2007 Synthesis, crystal structure and magnetic properties of a 1D mixed-metal-mixed-ligand Ni(II)/Fe(II) coordination polymer built on the nitroprusside anion. Inorg Chim Acta 360:28462850 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Bieńko, A, Kłak, J, Mroziński, J, Domagała, S, Korybut-Daszkiewicz, B, Woźniak, K 2007 Magnetism and crystal structures of CuIIMnII and CuIINiII ordered bimetallic chains. Polyhedron. 26:50305038 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Shebl, M 2009 Synthesis, spectral and magnetic studies of mono- and bi-nuclear metal complexes of a new bis(tridentate NO2) Schiff base ligand derived from 4,6-diacetylresorcinol and ethanolamine. Spectrochim Acta A 73:313323 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Zeybek, B 2009 Meltem Ates B, Ercan F, Levent Aksu M, Kılıc E¸ Atakol O. The effect of ligand basicity on the thermal stability of heterodinuclear NiII–ZnII complexes. J Therm Anal Calorim 98:377385 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Olar, R, Badea, M, Marinescu, D, Lazar, V, Chifiriuc, C 2009 New complexes of Ni(II) and Cu(II) with Schiff bases functionalised with 1,3,4-thiadiazole: spectral, magnetic, biological and thermal characterisation. J Therm Anal Calorim 97:721727 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Gaber, M, Rehab, AF, Badr-Eldeen, DF 2008 Spectral and thermal studies of new Co(II) and Ni(II) hexaaza and octaaza macrocyclic complexes. J Therm Anal Calorim 91:957962 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Kolinski, RA, Korybut-Daszkiewicz, B 1969 Isomeric 5,12-dimethyl-1,4,8,11-tetraazacyclotetradecanes and their nickel(II)complexes. Bull Acad Polon Sci Ser Sci Chim. 17:1318.

    • Search Google Scholar
    • Export Citation
  • 15. Kolinski, RA, Korybut-Daszkiewicz, B 1975 Macrocyclic ligands and their metal ion complexes. Part VI. preparation, stereochemistry and conformational analysis of polyalkyl-1,4,8,11-tetra-azacyclotetradeca-4,11-dienenickel(II) diperchlorates. Inorg Chim Acta 14:237245 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Gluzinski, P, Kolinski, RA, Krajewski, JW, Andreetti, GW, Bocelli, G 1991 X-ray structural investigation of N-epimeric, 1,8-cis- and 1,8-trans-5,12-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dienenickel(II) diperchlorates, C12H24N4Ni(ClO4)2. J Crystallogr Spectrosc Res 21:145151 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 17. Marchewka, MK, Drozd, M, Pietraszko, A 2003 Structure, spectra and phase transition in p-nitroanilinium perchlorate crystal. Mater Sci Eng B 100:225233 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Briget Mary, M, Umadevi, M, Pandiarajan, S, Ramakrishnan, V 2004 Vibrational spectral studies of l-methionine l-methioninium perchlorate monohydrate. Spectrochim Acta A. 60:26432651 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Nakamoto, K 2009 Infrared and Raman spectra of inorganic and coordination compounds Part A. Theory and applications in inorganic chemistry 6 Wiley New York.

    • Search Google Scholar
    • Export Citation
  • 20. Solymosi, F, Raskó, J 1977 Study of thermal decomposition of some transition metal perchlorates. J Therm Anal 11:289304 .

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2021 0 0 0
Jul 2021 0 0 0
Aug 2021 1 0 0
Sep 2021 0 0 0
Oct 2021 0 0 0
Nov 2021 1 0 1
Dec 2021 0 0 0