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  • 1 Institute of Chemistry, Jan Kochanowski University in Kielce, 15G Świętokrzyska Str, 25-406, Kielce, Poland
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Abstract

To compare thermal stability of Co(II), Zn(II), and Cd(II) complexes with 4-CHO-5-MeIm, the two compounds of formula [MnL2(NO3)2] and [NiL3](NO3)2 have been prepared and structurally characterized. Elemental analysis and spectroscopic studies have confirmed a bidentate fashion of coordination of the ligand to Mn(II) and Ni(II) ions. IR and Raman spectra indicate that there are different coordination modes of the NO3 in compounds: non-coordinated and coordinated. The decomposition process of the studied complexes in nitrogen and argon (Ni(II) complex) atmosphere proceeds in three main stages, except Zn(II) complex, in temperature range 353–1163 K. The final products of decomposition are CoO, MnO, Cd, ZnN4, NiN3. In addition, we have to admit that the different coordination mode of the NO3 ions in complexes: non-coordinated (in the (1), (4), and (5)) and coordinated (in the (2) and (3)) correlate with its thermal behavior. Thus, temperature ranges of its decompositions are observed: below 533 K and above 533 K, respectively. In Co(II), Mn(II), and Cd(II) complexes the fragments of N-donor atom-containing ligands decompose in the last stages, contrary to Zn(II) and Ni(II) compounds, in which metal ion surrounded by N atoms remains until the end. The course of pyrolysis and molecular structure of the complexes lead to the same conclusion about the strength of metal–ligand bonds. On the basis of obtained results, it is concluded that the thermal stability of the studied compounds follows the order: (1) < (5) < (2) < (3) < (4).

  • 1. Barszcz, B, Hodorowicz, S, Stadnicka, K, Jabłońska-Wawrzycka, A 2005 A comparison of the coordination geometries of some 4-methylimidazole-5-carbaldehyde complexes with Zn(II), Cd(II) and Co(II) ions in the solid state and aqueous solution. Polyhedron 24:627637 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Gockel, P, Vogler, R, Gelinsky, M, Meißner, A, Albrich, H, Vahrenkamp, H 2001 Zinc complexation of cyclic dipeptides containing cysteine and/or histidine. Inorg Chim Acta 323:1622 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Adult, DS 2001 Zinc coordination sphere in biochemical zinc sites. Biometals 14:271313 .

  • 4. Adult, DS 2009 The ins and outs of biological zinc sites. Biometals 22:141148 .

  • 5. Christianson, DW, Lipscomb, WN 1986 X-ray crystallographic investigation of substrate binding to carboxypeptidase A at subzero temperature. Proc Natl Acad Sci USA 83:75687572 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Christianson, DW, Cox, JD 1999 Catalysis by metal-activated hydroxide in zinc and manganese metalloenzymes. Annu Rev Biochem 68:3357 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Müller B , Vahrenkamp H. Zinc complexes of chelating aldehydes. Eur J Inorg Chem 1999; 13744.

  • 8. Hoog, JO, Hedberg, JJ, Stromberg, P, Svensson, S 2001 Mammalian alcohol dehydrogenase—functional and structural implications. J Biomed Sci 8:7176 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Dowling, C, Parkin, G 1996 Elaboration of the bis(pyrazolyl)hydroborato ligand [BpBut, Pri] into the NNO donor ligand, [(MeO)BpBut, Pri]: structural characterization of a complex in which the [(MeO)BpBut, Pri] ligand models the binding of zinc to the peptide backbone in thermolysin. Polyhedron 15:24632465 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Adams, H, Bradshaw, D, Fenton, DE 2002 A co-ordination number asymmetric dinuclear zinc(II) complex of an unsymmetrical compartmental proligand. Polyhedron 21:19571960 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Gunnlaugsson, T, Nieuwenhuyzen, M, Nolan, C 2003 Synthesis, X-ray crystallographic, spectroscopic investigation and cleavage studies of HPNP by simple bispyridyl iron, copper, cobalt, nickel and zinc complexes as artificial nucleases. Polyhedron 22:32313242 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Weder, JE, Dillon, CT, Hambley, TW, Kennedy, BJ, Lay, PA, Biffin, JR, Regtop, HL, Davies, NM 2002 Copper complexes of non-steroidal anti-inflammatory drugs: an opportunity yet to be realized. Coord Chem Rev 232:95126 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Milanino, R, Mauro, U, Marrella, M, Pasqualicchio, M, Gasperini, R, Velo, G 1995 G Berthon eds. Handbook of metal–ligand interactions in biological fluids Marcel Decker New York 886.

    • Search Google Scholar
    • Export Citation
  • 14. Casella, L, Gullotti, M 1993 Dioxygen activation by biomimetic dinuclear complexes KD Karlin Z Tyeklar eds. Bioinorganic chemistry of copper Chapman & Hall New York 292305 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. Liang, HC, Dahan, M, Karlin, KD 1999 Dioxygen-activating bio-inorganic model complexes. Curr Opin Chem Biol 3:168175 .

  • 16. Mahadevan, V, Gebbink, RJMK, Stack, TDP 2000 Biomimetic modeling of copper oxidase reactivity. Curr Opin Chem Biol 4:228234 .

  • 17. Zhang, F, Shen, L 2010 Synthesis, characterization and SOD activity of manganese(II) complexes with aza-macrocyclic ligand. J Chem Crystallogr 40:681685 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Lee, H, Park, W, Lim, D 2010 Synthesis and SOD activity of manganese complexes of substituted pyridino pentaaza macrocycles that contain axial auxiliary. Bioorg Med Chem Lett 20:24212424 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Singh, UP, Tyagi, P, Upreti, S 2007 Manganese complexes as models for manganese-containing pseudocatalase enzymes: Synthesis, structural and catalytic activity studies. Polyherdon 26:36253632 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Jarenmark, M, Carlsson, H, Nordlander, E 2007 Asymmetric dinuclear metal complexes as models for active sites in hydrolases and redox enzymes. C R Chimie 10:433462 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21. Barszcz, B, Głowiak, T, Jabłońska-Wawrzycka, A 2005 Ligation of alkoxymethylimidazoles towards cadmium(II) and zinc(II). X-ray, spectroscopic, thermal and potentiometric investigation. Trans Met Chem 30:221228 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Barszcz, B, Hodorowicz, S, Jabłońska-Wawrzycka, A, Stadnicka, K 2005 Synthesis, X-ray structure and spectroscopic investigation of eight-coordinate cadmium (II) complex. J Coord Chem 58:203208 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 23. Jabłońska-Wawrzycka A , Zienkiewicz M, Masternak J, Rogala P. Novel eight-coordinated Cd(II) complexes with two homologous pyridine alcohols. Crystal structure, spectroscopic and thermal properties. J Mol Struct 2012;1012: 97104.

    • Search Google Scholar
    • Export Citation
  • 24. Barszcz, B, Jabłońska-Wawrzycka, A, Stadnicka, K, Hodorowicz, S 2005 The synthesis and structural characterization of novel zinc and cadmium complexes of chelating alcohol. Inorg Chem Commun 8:951954 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 25. Barszcz, B, Masternak, J, Surga, W 2010 Thermal properties of Ca(II) and Cd(II) complexes of pyridinedicarboxylates. J Therm Anal Cal 101:633639 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 26. Barszcz, B, Hodorowicz, M, Jabłońska-Wawrzycka, A, Masternak, J 2010 Comparative study on Cd(II) and Ca(II) model complexes with pyridine-2,3-dicarboxylic acid: Synthesis, crystal structure and spectroscopic investigation. Polyhedron 29:11911200 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 27. Jabłońska-Wawrzycka, A, Barszcz, B, Stadnicka, K 2010 Similarities and differences of thermal behaviour of 2-hydroxymethylbenzimidazole complexes with Zn(II) and Cd(II) ions. J Therm Anal Cal 101:463469 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 28. Bal, W, Kozlowski, H, Kasprzak, KS 2000 Molecular models in nickel carcinogenesis. J Inorg Biochem 79:213218 .

  • 29. Minang, JT, Ahlborg, N, Troye-Blomberg, M 2003 A simplified ELISpot assay protocol used for detection of human interleukin-4, interleukin-13 and interferon-γ production in response to the contact allergen nickel. Exogenous Dermatol 2:306313 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 30. Jakobson, E, Masjedi, K, Ahlborg, N 2002 Cytokine production in nickel-sensitized individuals analysed with enzyme-linked immunospot assay: possible implication for diagnosis. Br J Dermatol 147:442449 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 31. Toebak, MJ, Pohlmann, PR, Sampat-Sardjoepersad, SC 2006 CXCL8 secretion by dendritic cells predicts contact allergens from irritants. Toxicol In Vitro 20:117124 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 32. Barszcz, B, Głowiak, T, Jezierska, J 1999 Crystal and molecular structures of eight-coordinate (CuN4O4) and six-coordinate (CuN4O2) Cu(II) complexes with 4-methyl-5-imidazole-carboxaldehyde or 1-benzyl-2-hydroxymethylimidazole, respectively. Polyhedron 18:37133721 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 33. Nakamoto, K 2009 Infrared and Raman spectra of inorganic and coordination compounds 6 Wiley Hoboken.

  • 34. Lever, ABP, Mantovani, E, Ramaswamy, BS 1971 Infrared combination frequencies in coordination complexes containing nitrate groups in various coordination environment. A probe for the metal-nitrate interaction. Can J Chem 49:19571964 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 35. Khalil, MMH, Ismail, EH, Abdel Azim, S, Souaya, ER 2010 Synthesis, characterization, and thermal analysis of ternary complexes of nitrilotriacetic acid and alanine or phenylalanine with some transition metals. J Therm Anal Calorim 101:129135 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 36. Soliman, MH, Mohamed, GG, Mohamed, EA 2010 Metal complexes of fenoterol drug. Preparation, spectroscopic, thermal, and biological activity characterization. J Therm Anal Calorim 99:639647 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 37. Doğan, F, Ulusoy, M, Öztürk, ÖF, Kaya, İ, Salih, B 2009 Thermal studies of Co(II), Ni(II) and Cu(II) complexes of N, N’-bis(3,5-di-t-butylsalicylidene)ethylenediamine. J Therm Anal Cal 96:267276 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 38. Powder Diffraction File, JCPDS: ICDD, 1601 Park Lane, Swarthmore, PA 19081, Data 1990, File No 9-402.

  • 39. Mazur, M, Gontarz, Z 2010 Reactions of manganese oxides with K2S2O7. J Therm Anal Calorim 100:993998 .

  • 40. Dose, WM, Donne, SW 2011 Kinetic analysis of γ-MnO2 thermal treatment. J Therm Anal Calorim 105:113122 .

  • 41. Powder Diffraction File, JCPDS: ICDD, 1601 Park Lane, Swarthmore, PA 19081, Data 1990, File No 7-230.

  • 42. Singh, G, Singh, CP, Frohlich, R 2006 Preparation, characterization and thermolysis of metal nitrate complexes with 4,4′-bipyridine. J Therm Anal Cal 85:425431 .

    • Crossref
    • Search Google Scholar
    • Export Citation

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  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
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  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)