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  • 1 Department of Chemistry, Inorganic Technology and Fuels, Silesian University of Technology, B. Krzywoustego 6, 44-100, Gliwice, Poland
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Abstract

Kinetic or rather thermokinetic analysis of thermal decomposition with releasing gaseous products is a current subject of discussion in many works and still devotes much attention to the property and meaningfulness of the single kinetics triplet determination. Analysis of thermogravimetric data by the relative rate of reaction/process were used to examine the frequently studied process of thermal dissociation of calcium carbonate as a model compound and comparing with published data for chemically defined compounds (azo-peroxyesters) and complex polyolefins–liquid paraffin mixtures. Two methods of correlation between parameters of the model were observed: thermodynamic and analytical expression. It was shown that these relations depend on course of the process. For analyzed model substance, enthalpy of reaction can be deduced on the basis of relation between coefficients in three-parameter equation. For large values of coefficients it is not possible, but other type of correlation was proved. Also, the relative rate of CO2 gasification (Boudouard reaction) of brown and bituminous coals was analyzed and compared to that of its pyrolysis.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)