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  • 1 Kamban Engineering College, Thiruvannamalai 606604, India
  • | 2 Department of Physics, Annamalai University, Annamalai Nagar 608002, India
  • | 3 P.G and Research Department of Physics, Government arts college, Thiruvannamalai 606604, India
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Abstract

A new semi organic Non-linear optical (NLO) crystal thiourea urea magnesium chloride (TUMC) was grown by slow evaporation technique at room temperature. Good quality single crystals were grown within 20 days. The FTIR spectrum of title compound was recorded and vibrational assignments were made. The recorded UV–vis spectrum shows the optical transmission property of the crystal. The Second harmonic generation (SHG) of TUMC crystal was tested by Kurtz–Perry method using Nd:YAG laser and the result confirms that the grown crystal exhibits NLO property. To analyse the thermal stability of the crystal TG/DTA analysis were made. Detailed structural analysis of the compound is under progress.

  • 1. Boyd, RW 1992 Non-linear optics Academic Press San Diego 155.

  • 2. Prasad, PN, Williams, DJ 1991 Introduction to nonlinear optical effects in organic molecules John Wiley & sons New York.

  • 3. Singh, N, Singh, BK, Sinha, N, Kumar, B 2008 Growth and characterization of new nonlinear optical thiourea l-alanine acetate crystal. J Cryst Growth 310:4487 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Wang, XQ, Xu, D DR Yuan Tian, YP, Yu, WT, Sun, SY, Yang, ZH, Fang, Q, Lu, MK, Yan, YX, Meng, FQ, Guo, SY, Zhang, GH, Jiang, MH 1999 Synthesis, structure and properties of a new nonlinear optical material: zinc cadmium tetrathiocyanate. Mater Res Bull 34:20032011 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Zhang, HW, Batra, AK, Lal, RB 1994 Growth of large methyl-(2,4-dinitrophenyl)- aminopropanoate: 2-methyl-4-nitroaniline crystals for nonlinear optical applications. J Cryst Growth 137:141 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Shen, J, Zheng, JM, Che, YX, Xi, B 2003 Growth and properties of organic nonlinear optical crystals: l-tartaric acid–nicotinamide and d-tartaric acid–nicotinamide. J Crys Growth 257:136 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7. Zhang, Y, Wang, Y, Cheand, Y, Zheng, J 2007 Growth and properties of two new organic nonlinear optical crystals: hydroxyethylammonium-l-tartrate monohydrate and hydroxyethylammonium-d-tartrate monohydrate. J Cryst Growth 299:120 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Gunasekaran, S, Anand, G, Venkatesan, J 2009 Crystal growth, comparison of vibrational and thermal properties of semi organic nonlinear optical materials. Arc Apl Sci Res 1 2 8185.

    • Search Google Scholar
    • Export Citation
  • 9. Madhurambal, G, Mariappan, M 2010 Growth and characterization of urea-thiourea non-linear optical organic mixed crystal. Indian J Pure Appl Phys 48:264270.

    • Search Google Scholar
    • Export Citation
  • 10. Ravindiran, R, Madhurambal, G, Mariappan, M 2011 Synthesis and characterization of some single crystals of thiourea urea zinc chloride. J Therm Anal Calorim 104 3 893899 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11. Mariappan, M, Madhurambal, G, Ravindiran, R 2011 Thermal, FTIR and micro hardness studies of bis thiourea urea single crystals. J Therm Anal Calorim 104 3 915921 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12. Ushasree, PM, Jayavel, R 1999 Growth of zinc thiourea sulfate (ZTS) single crystals: a potential semiorganic NLO material. J Cryst Growth 197:216220 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Rajasekaran, R, Ushasree, PM, Jayavel, R, Ramasamy, P 2001 Growth and characterization of zinc thiourea chloride (ZTC): a semi organic nonlinear optical crystal. J Cryst Growth 229:563567 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Gunasekaran, S, Anand, G, Arunbalaji, R, Kumaresan, S 2010 Crystal growth and comparison of vibrational and thermal properties of semi organic nonlinear optical materials. Pramana J Phys 75:683690 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. Ramajothi, J, Dhanuskodi, S, Nagarajan, K 2004 Crystal growth, thermal, optical and microhardness studies of tris (thiourea) zinc sulphate—a semiorganic NLO material. Cryst Res Technol 39:414420 .

    • Crossref
    • Search Google Scholar
    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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