Geopolymers
Inorganic polymeric new materials
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Murat Turkyilmaz
Murat Turkyilmaz
Department of Chemistry, Science Faculty, Trakya University, Edirne, Turkey
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Alper Onder
Alper Onder
Department of Chemistry, Art and Science Faculty, Onsekiz Mart University, Canakkale, Turkey
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Yakup Baran
Yakup Baran
Department of Chemistry, Art and Science Faculty, Onsekiz Mart University, Canakkale, Turkey
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Abstract
Four polydentate azomehines and their mono- and binuclear Pt(II), Cu(II), and Ni(II) complexes were synthesized and characterized. The resulting complexes were characterized by FTIR, magnetic measurements, elemental analysis, conductivity measurements, and thermal analysis. Electronic spectra and magnetic susceptibility measurements sustain the proposed distorted square-planar structures for the copper complexes. The electronic spectra display the characteristic pattern of square-planar stereochemistry for the other complexes. The thermal analyses have evidenced the thermal intervals of stability and also the thermodynamic effects that accompany them. Azomethine complexes have a similar thermal behavior for the selected metal ions. The decomposition processes as water elimination, chloride anion removal as well as degradation of the organic ligands were observed.
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1. Pouralimardan, O, Chamayou, AC, Janiak, C, Monfared, HH 2007 Hydrazone Schiff base-manganese(II) complexes: synthesis, crystal structure and catalytic reactivity. Inorg Chim Acta 360:1599–1608 .
-
2. Sen S , Talukder P, Dey SK, Mitra S, Rosair GM, Hughes DL, Yap GPA, Pilet G, Gramlich V, Matsushita T. Ligating properties of a potentially tetradentate Schiff base [(CH3)2NCH2CH2N=CHC6H3(OH)(OMe)] with zinc(II),cadmium(II), cobalt(II), cobalt (III) and manganese(III) ions: synthesis and structural studies. J Chem Soc Dalton Trans. 2006; 1758–1767.
-
3. Mastrolorenzo, A, Scozzafava, A, Supuran, CT 2001 Arylsulfonyl-N,N-dialkyl-dithio carbamates as tumor cell growth inhibitors: novel agents targeting-tubulin. J Enzyme Inhib 16:54–65.
-
4. Chohan, ZH, Pervez, H, Rauf, A, Scozzafava, A, Supuran, CT 2002 Antibacterial Co(II), Cu(II), Ni(II) and Zn(II) complexes of thiadiazole derived furanyl, thiophenyl and pyrrolyl Schiff bases. J Enzyme Inhib 17:117–122 .
-
5. Chohan, ZH, Pervez, H, Rauf, A, Supuran, CT 2002 Antibacterial role of SO4 2−, NO3−, C2O4 2− and CH3COO− anions on Cu(II) and Zn(II) complexes of thiadiazole-derived pyrrplyl Schiff bases. Met Based Drugs 8:263–267 .
-
6. Costes, JP, Dahan, F, Dupius, A 2000 Influence of anionic ligands (X) on the nature and magnetic properties of dinuclear LCuGdX3 center dot nH(2)O complexes (LH2 standing for tetradentate Schiff base ligands deriving from 2-hydroxy-3-methoxybenzaldehyde and X being Cl, N3C2, and CF3COO). Inorg Chem 39:165–168 .
-
7. West, DX, Swearingen, JK, Valde′s-Martinez, J, Hernandez-Ortega, S, El-Sawaf, AK, Van Meurs, F, Castineiras, A, Garcia, I, Bermejo, E 1999 Spectral and structural studies of iron(III), cobalt(II, III) and nickel(II) complexes of 2-pyridineformamide N(4)-methyl thio semicarbazone. Polyhedron 18:2919–2929 .
-
8. Tarasconi, P, Capacchi, S, Pelosi, G, Cornia, M, Albertini, R, Bonati, A, Dall’ Aglio, PP, Lunghi, P, Pinelli, S 2000 Synthesis, spectroscopic characterization and biological properties of new natural aldehydes thiosemicarbazones. Bioorg Med Chem 8:157–162 .
-
9. Ackerman, LJ, Fanwick, PE, Green, MA, John, E, Running, WE, Swearingen, JK, Webb, JW, West, DX 1999 Structural and spectral studies of copper(II) and nickel(II) complexes of pyruvaldehyde mixed bis{N(4)-substituted thiosemicarbazones}. Polyhedron 18:2759–2767 .
-
10. Sartorelli, AC, Agarwal, KC, Tsiftsoglou, AS, Moore, EC 1977 Characterization of the biochemical mechanism of action of α-(N)-heterocyclic carboxaldehyde thiosemi carbazones. Adv Enzyme Regul 15:117–139 .
-
11. Teoh, SG, Ang, SH, Fun, HK, Ong, CW 1999 Synthesis, crystal structure and biological activity of thiophene-2-carboxaldehyde thiosemicarbazone and its tin complexes. J Organomet Chem 580:17–23 .
-
12. Chohan, ZH, Scozzafava, A, Supuran, CT 2002 Unsymmetrical 1,1′-disubstituted ferrocenes: synthesis of Co(II), Cu(II), Ni(II) and Zn(II) chelates of ferrocenyl-1-thiadiazolo-1′-tetrazole, -1-thiadiazolo-1′-triazole and -1-tetrazolo-1′-triazole with antimicrobial properties. J Enzyme Inhib Med Chem 17:261–266 .
-
13. Singh, HL, Sharma, M, Varshney, AK 2000 Studies on coordination compounds of organotin(IV) with schiff bases of amino acids. Synth React Inorg Met-Org Chem 30 3 445–456 .
-
14. Nath, M, Pokharia, S, Yadav, R 2001 Organotin(IV) complexes of amino acids and peptides. Coord Chem Rev 215:99–149 .
-
15. Chohan, ZH, Praveen, M, Ghaffer, A 1997 Structural and biological behaviour of Co(II), Cu(II) and Ni(II) metal complexes of some amino acid derived schiff-bases. Met-Based Drugs 4:267–272 .
-
16. Lv, J, Liu, T, Cai, S, Wang, X, Liu, L, Wang, Y 2006 Synthesis, structure and biological activity of cobalt(II) and copper(II) complexes of valine-derived schiff bases. J Inorg Biochem 100:1888–1896 .
-
17. Coghi L , Lanferdi AMM, Tiripicchio A. Crystal and molecular structure of thiosemicarbazide hydrochloride. J Chem Soc Perkin II. 1976; 1808–10.
-
18. Kasai, K, Aoyagi, M, Fujita, M 2000 Flexible coordination networks with fluorinated backbones. remarkable ability for ınduced-fit enclathration of organic molecules. J Am Chem Soc 122 9 2140–2141 .
-
19. Kitagawa, S, Kitaura, R, Noro, SI 2004 Functional porous coordination polymers. Angew Chem Int Ed 43 18 2334–2375 .
-
20. Hoshino, N, Ito, T, Nihei, M, Oshio, H 2003 Syntheses, structures and magnetic properties of multinuculear manganese complexes with Schiff base ligands. Inorg Chem Commun 6 4 377–380 .
-
21. Khandar, AA, Nejati, K 2000 Synthesis and characterization of a series of copper(II) complexes with azo-linked salicylaldimine Schiff base ligands. Polyhedron 19 6 607–613 .
-
22. Zhou, HP, Li, DM, Wang, P, Cheng, LH, Gao, YH, Zhu, YM, Wu, JY, Tian, YP, Tao, XT, Jiang, MH, Fun, HK 2007 Synthesis, crystal structures, and two-photon absorption properties of dithiocarbazate Zn(II) and Pd(II) complexes. J Mol Struct 826 3 205–210 .
-
23. Chan, WK 2007 Metal containing polymers with heterocyclic rigid main chains. Coord Chem Rev 251:2104–2118 .
-
24. Vigato, PA, Tamburini, S 2008 Advances in acyclic compartmental ligands and related complexes. Coord Chem Rev 252:1871–1995 .
-
25. Lodeiro, C, Pina, F 2009 Luminescent and chromogenic chemosensors based on polyamine and related compounds. Coord Chem Rev 253:1353–1383 .
-
26. Basak, S, Sen, S, Mitra, S, Marschner, C, Sheldrick, WS 2008 Square planar complexes of Cu(II) and Ni(II) with N2O donor set of two Schiff base ligands: synthesis and structural aspects. Struct Chem 19:115–121 .
-
27. Fan, YH, Gao, ZX, Bi, CF, Xie, ST, Zhang, X 2008 Synthesis and thermal decomposition kinetics of La(III) complexwith unsymmetrical Schiff base ligand. J Therm Anal Calorim 91:919–923 .
-
28. Patel, SH, Pansuriya, PB, Chhasatia, MR, Parekh, HM, Patel, MN 2008 Coordination chain polymeric assemblies of trivalent lanthanides with multidentate Schiff base synthetic, spectral investigation and thermal aspects. J Therm Anal Calorim 91:413–418 .
-
29. Lalia-Kantouri, M, Tzavellas, L, Paschalidis, D 2008 Novel lanthanide complexeswith di-2-pyridyl ketone-p-chloro-benzoylhydrazone. J Therm Anal Calorim 91:937–942 .
-
30. Nakamoto, K 1978 Infrared and Raman spectra of inorganic and coordination compounds 3 242 Wiley New York.
-
31. Surati, KR, Thaker, BT 2006 Synthesis, spectroscopic and thermal investigation of Schiff-base complexes of Cu(II) derived from heterocyclic β-diketone with various primary amines. J Coord Chem 59:1191–1202 .
-
32. Ferraro, JR 1971 Low frequency vibrations of inorganic and coordination compounds Plenum Press New York.
-
33. Natarajan, C, Tharmaraj, P, Murugesan, R 1992 In situ synthesis and spectroscopic studies of copper(II) and nickel(II) complexes of 1-hydroxy-2-naphthylstyrylketoneimines. J Coord Chem 26:205–213 .
-
34. Dehghanpour, S, Bouslimani, N, Welter, R, Mojahed, F 2007 Synthesis, spectral charac terization, properties and structures of copper(I) complexes containing novel bidentate iminopyridine ligands. Polyhedron 26:154–162 .
-
35. Samanta, B, Chakraborty, J, Shit, S, Batten, SR, Jensen, P, Masuda, JD, Mitra, S 2007 Synthesis, characterisation and crystal structures of a few coordination complexes of nickel(II), cobalt(III) and zinc(II) with N′-[(2-pyridyl)methylene]salicyloylhydrazone Schiff base. Inorg Chim Acta 360:2471–2481 .
-
36. Ray, A, Banerjee, S, Butcher, RJ, Desplanches, C, Mitra, S 2008 Two new end-on azido bridged dinuclear copper and cobalt(II) complexes derived from the (E)-N′-((pyridine-2-yl)methylene acetohydrazide Schiff base ligand: characterisation, crystal structure and magnetic study. Polyhedron 27:2409–2415 .
-
37. Del Paggio, AA, McMillin, DR 1983 Substituent effects and the photoluminescence of Cu(PPh3)2(NN)+ systems. Inorg Chem 22:691–692 .
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
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| Founder | Akadémiai Kiadó |
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H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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