Abstract
Two series of styrene monomers, one with phosphorus-containing moieties as substituents and the other with substituents containing both phosphorus and nitrogen, have been prepared, characterized, and converted to oligomers. The oligomers contain, in the one case, phosphorus and, in the other, phosphorus and nitrogen. This provides the opportunity to not only assess the impact of the presence of phosphorus on the combustion characteristics of the oligomers but to determine whether or not this impact is enhanced by the presence of nitrogen. The level of residue from thermogravimetry and heat release rate during combustion suggest that the presence of nitrogen may have a small positive impact on the effectiveness of phosphorus flame retardants.
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1. Vahabi H , Longuet C, Ferry L, David G, Robin J-J, Lopez-Cuesta J-M. Effect of aminobisphosphonated copolymer on the thermal stability and flammability of poly(methyl methacrylate). Polym Int. 2011. doi: .
-
2. Lui, Y, Zhao, J, Dong, C-L, Wang, D-Y, Wang, Y-Z 2011 Flame retardant effect of Sepiolite on an intumescent flame-retardant polypropylene system. Ind Eng Chem Res 50:2047–2054 .
-
3. Qu H , Wu W, Xie J, Xu J. A novel intumescent flame retardant and smoke suppression system for flexible PVC. Polym Adv Technol. 2011. doi: .
-
4. Zhang W , Li X, Yang R. Flame retardancy mechanisms of phosphorus-containing polyhedral oligomeric silsesquioxane (DOPO-POSS) in polycarbonate/acrylonitrile-butadiene-styrene blends. Polym Adv Technol. 2011. doi: .
-
5. Konig, A, Kroke, E 2011 Methyl-DOPO—a new flame retardant for flexible polyurethane foam. Polym Adv Technol 22:5–13 .
-
6. Yang, W, Song, L, Hu, Y, Lu, H, Yuen, RKK 2011 Investigation of thermal degradation behavior and fire performance of halogen-free flame retardant poly(1,4-butylene terephthalate) composites. J Appl Polym Sci 122:1480–1488 .
-
7. Li, H, Zhu, H, Li, J, Fan, X, Tian, X 2011 Thermal degradation behavior of phosphorus–silicon synergistic flame-retardant copolyester. J Appl Polym Sci 122:1993–2033 .
-
8. Kaynak, C, Isitman, NA 2011 Synergistic fire retardancy of colemanite, a natural hydrated calcium borate, in high-impact polystyrene containing brominated epoxy and antimony oxide. Polym Degrad Stab 96:798–807 .
-
9. Hu Z , Lin G-P, Chen L, Wang Y-Z. Flame retardation of glass-fiber-reinforced polyamide 6 by combination of aluminum phenylphosphinate with melamine pyrophosphate. Polym Adv Technol. 2011. doi: .
-
10. Patel, P, Hull, TR, Stee, AA, Lyon, RE 2011 Influence of physical properties on polymer flammability in the cone calorimeter. Polym Adv Technol 22:1100–1107 .
-
11. Schartel, D, Hull, TR 2007 Application of cone calorimetry to the development of materials with improved fire performance. Fire Mater 31:327–354 .
-
12. Lyon, RE, Walters, RN 2004 Pyrolysis combustion flow calorimetry. J Anal Appl Pyrolysis 71 1 27–46 .
-
13. Schartel, B, Pawlowski, KH, Lyon, RE 2007 Pyrolysis combustion flow calorimeter: a tool to assess flame retarded PC/ABS materials?. Therm Acta 462 1–2 1–14 .
-
14. Stoliarov, SI, Walters, RN, Lyon, RE 2007 A method for constant-rate heating of milligram-sized samples. J Therm Anal Calorim 89 2 367–371 .
-
15. Cogen, JM, Lin, TS, Lyon, RE 2009 Correlations between pyrolysis combustion flow calorimetry and conventional flammability tests with halogen-free flame retardant polyolefin compounds. Fire Mater 33 1 33–50 .
-
16. V Babrauskas SJ Grayson eds. 1992 Heat release in fires E&FN Spon (Chapman and Hall) London.
-
17. Babrauskas, V, Peacock, RD 1992 Heat release rate: the single most important variable in fire hazard. Fire Saf J 18 3 255–272 .
-
18. ASTM D7309. Determining flammability characteristics of plastics and other solid materials using microscale combustion calorimetry. 2007.
-
19. Dumitrascu, A, Howell, BA 2011 Flame-retarding vinyl polymers using phosphorus-functionalized styrene monomers. Polym Degrad Stab 96 3 342–349 .
-
20. Dumitrascu A , Howell BA. Impact of the incorporation of the nitrogen into phosphorus flame retardant styrene monomers. In: Proceedings, 22nd annual conference on recent advances on flame retardancy of polymeric materials, Chap 10. Wellesley: BCC Research; 2011.
-
21. Levchik, SV, Weil, ED 2008 Review—new developments in flame retardancy of styrene thermoplastics and foams. Polym Int 57:431–448 .
-
22. Weil, ED, Levchik, SV 2007 Flame retardants for polystyrenes in commercial use or development. J Fire Sci 25:241–265 .
-
23. Furukawa, J, Kobayashi, E, Wakui, T 1980 Phosphorus-containing polystyrene derivatives for flame resistance. Polym J 12 5 277–285 .
-
24. Yu, Z, Zhu, W-E 1990 Synthesis and polymerization of vinylbenzylphosphonate diethyl ester. J Polym Sci Part A Polym Chem 28:227–230 .
-
25. Boutevin, B, Hamoui, B, Bessière, J-MM 1995 Synthesis of a phosphonated styrene monomer. Instability of the diacidic moiety and polymerization. Macromol Chem Phys 196:1865–1873 .
-
26. Ebdon, JR 1997 Flame retardancy in styrenic and acrylic polymers with covalently bound phosphorus-containing groups. Recent Adv Flame Retard Polym Mater 8:161–170.
-
27. Ebdon, JR, Price, D, Hunt, BJ, Joseph, P, Gao, F, Milnes, GJ, Cunlife, LK 2000 Flame retardance in some polystyrenes and poly(methyl methacrylate)s with covalently bound phosphorus-containing groups: initial screening experiments and some laser pyrolysis mechanistic studies. Polym Degrad Stab 69:267–277 .
-
28. Nguyen, C, Kim, J 2008 Synthesis of a novel nitrogen–phosphorus flame retardant based on phosphoramidate and its application to PC, PBT, EVA, and ABS. Macrom Res 16 7 620–625 .
-
29. Gao, F, Tong, L, Fang, Z 2006 Effect of a novel phosphorus–nitrogen containing intumescent flame retardant on the fire retardancy and the thermal behaviour of poly(butylene terephthalate). Polym Degrad Stab 91:1295–1299 .
-
30. Gaan S , Salimova V, Heuberger M, Rupper P, Schoenholzer. Phosphoramidate flame retardants: mechanism and application. In: BCC conference, May 2009.
-
31. Gaan, S, Mauclaire, L, Rupper, P, Salimova, V, Tran, T-T, Heuberger, M 2011 Thermal degradation of cellulose acetate in presence of bis-phosphoramidates. J Anal Appl Pyrolysis 90:33–41 .
-
32. Carbonneau, C, Frantz, R, Durand, J-O, Lanneau, GF, Corriu, RJP 1999 Efficient syntheses of new phosphonate terminated trialkoxysilane derived oligoarylenevinylene fluorophores. Tetrahedron Lett 40:5855–5858 .
-
33. Sugiono, E, Metzroth, T, Detert, H 2001 Practical synthesis of vinyl-substituted p-phenylenevinylene oligomers and their triethoxysilyl derivatives. Adv Synth Catal 343 4 551–559 .
-
34. Skaff, H, Ilker, MF, Coughlin, EB, Emrick, T 2002 Preparation of cadmium selenide–polyolefin composites from functional phosphine oxides and ruthenium-based metathesis. J Am Chem Soc 124 20 5729–5733 .
-
35. Frantz, R, Durand, J-O, Carré, F, Lanneau, GF J Le Bideau Alonso, B, Massiot, D 2003 Synthesis and solid-state NMR studies of P-vinylbenzylphosphonic acid. Chem A Eur J 9 3 770–775 .
-
36. Seferos, DS, Banach, DA, Alcantar, NA, Israelachvili, JN, Bazan, GC 2004 α,ω-Bis(thioacetyl)oligophenylenevinylene chromophores from thioanisol precursors. J Org Chem 69 4 1110–1119 .
-
37. Wyman, P, Crook, VL, Hunt, BJ, Ebdon, JR 2004 Improved synthesis of phosphorus-containing styrenic monomers. Des Monom Polym 7 3 301–309 .
-
38. Wyman, P, Crook, VL, Ebdon, J, Hunt, B, Joseph, P 2006 Flame-retarding effects of dialkyl-p-vinylbenzyl phosphonates in copolymers with acrylonitrile. Polym Int 55 7 764–771 .
-
39. Markova, D, Kumar, A, Müllen, K, Klapper, M 2006 Poly(vinylbenzyl phosphonic acid) homo and BAB-block copolymers as polymer electrolyte membranes for fuel cells. Prepr Symp Am Chem Soc Div Fuel Chem 51 2 651–652.
-
40. Britze, A, Moosmann, K, Jähne, E, Adler, H-J, Kuckling, D 2006 Synthesis of block copolymers modified with phosphonate ester groups using nitroxide-mediated radical polymerization. Macromol Rapid Comm 27 22 1906–1912 .
-
41. Alperstein, D, Kornberg, N, Knani, D 2011 A study of fire retardant blooming in HIPS by molecular modeling. Polym Adv Technol 22:1446–1451 .
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
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1969 |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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