Geopolymers
Inorganic polymeric new materials
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Xianhong Feng
Xianhong Feng
Medical Device Concept Laboratory, Department of Biomedical Engineering, New Jersey Institute of Technology, 111 Lock Street, Newark, NJ, 07103, USA
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Anthony East
Anthony East
Medical Device Concept Laboratory, Department of Biomedical Engineering, New Jersey Institute of Technology, 111 Lock Street, Newark, NJ, 07103, USA
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Willis Hammond
Willis Hammond
Medical Device Concept Laboratory, Department of Biomedical Engineering, New Jersey Institute of Technology, 111 Lock Street, Newark, NJ, 07103, USA
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Zohar Ophir
Zohar Ophir
Medical Device Concept Laboratory, Department of Biomedical Engineering, New Jersey Institute of Technology, 111 Lock Street, Newark, NJ, 07103, USA
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Yi Zhang
Yi Zhang
Medical Device Concept Laboratory, Department of Biomedical Engineering, New Jersey Institute of Technology, 111 Lock Street, Newark, NJ, 07103, USA
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Michael Jaffe
Michael Jaffe
Medical Device Concept Laboratory, Department of Biomedical Engineering, New Jersey Institute of Technology, 111 Lock Street, Newark, NJ, 07103, USA
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Abstract
Sugar-based new monomers, polymers, and low molar mass additives have emerged as an exciting topic on green chemistry research, due to the worldwide focus on sustainable material. Isosorbide and its isomers, as “Generally Recognized as Safe” GRAS materials, possess unique stereochemistry and molecular geometry suitable for making cost-effective chemicals and polymers. With growing awareness of bisphenol A (BPA) as a xenoestrogen, isosorbide and its isomers holding the remarkable chemical properties and attractive price can be attached to glycidyl ether to make crosslinkable epoxy resin monomers with similar properties to BPA diglycidyl ether. By adding the hydrophobic functional group into the backbone of isosorbide epoxy or adjusting the amount and type of crosslinker, the mechanical properties and the water uptake ratios (from <1 to >50 wt%) of the isosorbide-derived epoxies could be optimized for different applications. The high water uptake epoxy with controllable biodegradation rate could be used as a drug delivery system or extracellular matrix for biomedical applications while the low water uptake epoxy with strong mechanical properties could be used for can coatings, bone cements, and other industrial additives and adhesives. The chemical structures and properties of the synthesized epoxy monomers and polymers were characterized by DSC, TG, and 1H NMR.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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