Authors:
Lung-Chang TsaiDepartment of Safety Engineering, School of Chemical Engineering, Nanjing University of Science and Technology, 200, Xiao Ling Wei Street, Nanjing 210094, China, PRC

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Yun-Ting TsaiDepartment of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology, 123, University Rd., Sec. 3, Douliou, Yunlin 64002, Taiwan, ROC

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Chun-Ping LinDepartment of Health and Nutrition Biotechnology, College of Health Science, Asia University, 500, Lioufeng Rd., Wufeng, Taichung 41354, Taiwan, ROC

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Shang-Hao LiuDepartment of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology, 123, University Rd., Sec. 3, Douliou, Yunlin 64002, Taiwan, ROC

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Tsung-Chih WuDepartment of Safety, Health, and Environmental Engineering, Hungkuang University, 34, Chung-Chie Rd., Shalu, Taichung 43302, Taiwan, ROC

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Chi-Min ShuDepartment of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology, 123, University Rd., Sec. 3, Douliou, Yunlin 64002, Taiwan, ROC

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Abstract

Liquid organic peroxides have been broadly employed in the process industries such as tert-butyl peroxy-2-ethyl hexanoate (TBPO). This study investigated the thermokinetic parameters of TBPO, a typical liquid organic peroxide, by isothermal kinetic algorithms and non-isothermal kinetic algorithms with thermal activity monitor III, and differential scanning calorimetry, respectively. An attempt has been made to determine the thermokinetic parameters by simulation software, such as exothermic onset temperature (T0), maximum temperature (Tmax), decomposition (ΔHd), activation energy (Ea), self-accelerating decomposition temperature, and isothermal time to maximum rate (TMRiso). A liquid thermal explosion model was established for a reactor containing liquid organic peroxide of interest. From experimental results, liquid organic peroxides’ optimal conditions for avoiding a violent runaway reaction of storage and transportation were created.

  • 1. Lu, KT, Chen, TC, Hu, KH 2010 Investigation of the decomposition reaction and dust explosion characteristics of crystalline benzoyl peroxides. J Hazard Mater 161:246256 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Luo, KM, Chang, JG, Lin, SH, Chang, CT, Yeh, TF, Hu, KH, Kao, CS 2001 The criterion of critical runaway and stable temperatures in cumene hydroperoxide reaction. J Loss Prev Proc Ind 14:229239 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. United Nations, Committee of Experts on the Transport of Dangerous Goods, 14th Revised Ed., USA. 2005;205.

  • 4. Fisher, HG, Goetz, DD 1993 Determination of self–accelerating decomposition temperatures for self–reactive substances. J Loss Prev Proc Ind 6:183194 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Fauske HK . Gassy system vent sizing the role of two-phase flow. Process Safety News. Burr Bidge, IL: Fauske and Associates, LLC; 2011;18: 3.

    • Search Google Scholar
    • Export Citation
  • 6. Akts AG , AKTS-Thermokinetics Software and AKTS-Thermal Safety Software. http://www.akts.com.

  • 7. Material Safety Data Sheet. Akzo Nobel Chemicals bv Stationsplein, 4. P.O. Box 247, 3800 AE Amersfoort, The Netherlands; 2007.

  • 8. Wu, LK, Chen, KY, Cheng, SY, Lee, BS, Shu, CM 2008 Thermal decomposition of hydrogen peroxide in the presence of sulfuric acid. J Therm Anal Calorim 93:115120 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Hou, HY, Duh, YS, Lin, WH, Shu, CM 2006 Reactive incompatibility of cumene hydroperoxide mixed with alkaline solutions. J Therm Anal Calorim 85:145150 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10. Duh, YS, Wu, XH, Kao, CS 2008 Hazard ratings for organic peroxides. Process Saf Prog 27:8999 .

  • 11. Safety and handling of organic peroxides: a guide, organic peroxide producers’ safety division. The Society of the Plastics Industry (SPI) Inc., Washington, DC, USA. 1999.

    • Search Google Scholar
    • Export Citation
  • 12. Lin, CP, Chang, CP, Chou, YC, Shu, CM 2010 Modeling solid thermal explosion containment on reactor HNIW and HMX. J Hazard Mater 176:549558 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. STARe Software with Solaris Operating System. Operating Instructions. Toledo: Mettler Toledo; 2004.

  • 14. Product Information. 2012. TAM III Thermostat. www.thermometric.com.

  • 15. Lin, CP, Chang, YM, Tseng, JM, Shu, CM 2010 Comparisons of nth-order kinetic algorithms and kinetic model simulation on HMX by DSC tests. J Therm Anal Calorim 100:607614 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Thermal safety software (TSS). St. Petersburg, Russia: ChemInform Saint-Petersburg (CISP) Ltd. http://www.cisp.spb.ru.

  • 17. You, ML, Shu, CM 2011 Further explanations of lauroyl peroxide runaway reaction by DSC tests and simulations. J Therm Anal Calorim 103:411412 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Lin, CP, Tseng, JM 2012 Green technology for improving process manufacturing design and storage management of organic peroxide. Chem Eng J 180:284292 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 19. Peng, JJ, Wu, SH, Hou, HY, Lin, CP, Shu, CM 2009 Thermal hazards evaluation of cumene hydroperoxide mixed with its derivatives. J Therm Anal Calorim 96:783787 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20. Liu, SH, Lin, CP, Shu, CM 2011 Thermokinetic parameters and thermal hazard evaluation for three organic peroxides by DSC and TAM III. J Therm Anal Calorim 106:165172 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21. Tseng, JM, Liu, MY, Chen, SL, Hwang, WT, Gupta, JP, Shu, CM 2009 Runaway effects of nitric acid on methyl ethyl ketone peroxide by TAM III tests. J Therm Anal Calorim 96:789793 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22. Akzo Nobel , Organic Peroxide Initiators, Product Brochure, USA. 2012.

  • 23. Malow, M, Wehrstedt, KD 2005 Prediction of the self–accelerating decomposition temperature (SADT) for liquid organic peroxides from differential scanning calorimetry (DSC) measurements. J Hazard Mater 120:2124 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Lin, CP, Tseng, JM, Chang, YM, Liu, SH, Cheng, YC, Shu, CM 2010 Modeling liquid thermal explosion reactor containing tert–butyl peroxybenzoate. J Therm Anal Calorim 102:587595 .

    • Crossref
    • Search Google Scholar
    • Export Citation
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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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Author:
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