View More View Less
  • 1 Institute of Chemistry and Environmental Protection, West Pomeranian University of Technology, Al. Piastów 42, 71-065, Szczecin, Poland
  • | 2 Institute of Physics, Polish Academy of Sciences, Al. Lotników 32/46, 02-668, Warszawa, Poland
Restricted access

Abstract

Ilmenite is a valuable source of titanium and is applied as the main raw material in the technology of titanium white pigment production. Ilmenite is found in many places in the earth, and its elemental as well as phase compositions very strongly depend on the place of origin. Deposits located in Australia, China, India, and Norway in Europe are well known places where ilmenites are exploited industrially. Main phases that were identified in these ilmenites are ilmenite FeTiO3, hematite Fe2O3, geikielite MgTiO3 and pseudorutile Fe2Ti3O9. Enstatite MgSiO3, MnTiO3, and kleberite (determined also as hydroxylian pseudorutile with approximate formula FeTi3O6(OH)3) are minor phases present in ilmenites. Calorimetric investigations of reactions of these ilmenites with sulphuric acid in standard conditions demonstrated significant differences in the shape of temperature and thermal power curves. On the basis of these investigations, it can be concluded that the shape of the thermal power curve is different for each of ilmenite and can be treated as a fingerprint of their phase composite.

  • 1. Chernet, T 1999 Applied mineralogical studies on Australian sand ilmenite concentrate with special reference to its behaviour in the sulphate process. Miner Eng 12:485495 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 2. Zhang, L, Huiping, H, Liao, Z, Chen, Q, Ta, J 2011 Hydrochloric acid leaching behavior of different treated Panxi ilmenite concentrations. Hydrometallurgy 107:4047 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3. Zhang, L, Huiping, H, Wei, L, Chen, Q, Tan, J 2010 Hydrochloric acid leaching behaviour of mechanically activated Panxi ilmenite (FeTiO3). Sep Purif Technol 73:173178 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4. Liu, S-H, Lin, C-P, Shu, C-M 2011 Thermokinetic parameters and thermal hazard evaluation for three organic peroxides by DSC and TAM III. J Therm Anal Calorim 106:165172 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5. Lin, C-P, Tseng, J-M, Chang, Y-M, Liu, S-H, Cheng, Y-C, Shu, C-M 2010 Modeling liquid thermal explosion reactor containing tert-butyl peroxybenzoate. J Therm Anal Calorim 102:587595 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6. Jabłoński, M 2010 Investigation of thermal power of reaction of titanium slag with sulphuric acid. Cent Eur J Chem. 8:149154 .

  • 7. Klepka, M, Lawniczak-Jablonska, K, Jablonski, M, Wolska, A, Minikayev, R, Paszkowicz, W, Przepiera, A, Spolnik, Z R Van Grieken 2005 The composition of mineral ilmenite used in pigments production. J Alloy Compd. 401:281288 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8. Nayak, PK, Das, D, Chintalapudi, SN, Singh, P, Acharya, S, Vijayan, V, Chakravortty, V 2002 Quantitative multielemental analysis of titaniferous magnetites by PIXE, EDXRF, and their iron mineral characterization by Fe Mossbauer spectroscopy. J Radioanal Nucl Chem. 254:351356 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 9. Jabłoński, M, Przepiera, A 2001 Estimation of kinetic parameters of thermal oxidation of ilmenite. J Therm Anal Calorim 66:617622 .

  • 10. Jabłoński, M, Przepiera, A 2001 Kinetic model for the reaction of ilmenite with sulphuric acid. J Therm Anal Calorim 65:583590 .

  • 11. Liang, B, Li, C, Zhang, C, Zhang, Y 2005 Leaching kinetics of Panzhihua ilmenite in sulfuric acid. Hydrometallurgy. 76:173179 .

  • 12. Sasikumar, C, Rao, DS, Srikanth, S, Ravikumar, B, Mukhopadhyay, NK, Mehrotra, SP 2004 Effect of mechanical activation on the kinetics of sulfuric acid leaching of beach sand ilmenite from Orissa, India. Hydrometallurgy. 75:189204 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13. Zhang, G, Ostrovski, O 2002 Effect of preoxidation and sintering on properties of ilmenite concentrates. Int J Miner Process 64:201218 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14. Piskorska, E, Lawniczak-Jablonska, K, Klimczyk, P, Minikayev, R, Paszkowicz, W, Benko, E, Wolska, A 2007 Quantitative phase analysis of cubic boron nitride based composites by X-ray absorption near edge structure. Spectrochim Acta B. 62:461469 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15. Klepka, MT, Lawniczak-Jablonska, K, Wolska, A, Jablonski, M 2010 Identification of minority compounds in natural ilmenites by X-ray absorption spectroscopy. J Electron Spectrsc Rel Phenom. 182:8589 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16. Jabłoński, M, Przepiera, A 2006 Hazard in reaction of titanium raw materials with sulphuric acid. J Therm Anal Calorim 83:571573 .

  • 17. Jabłoński, M 2009 Influence of particle size distribution on thermokinetics of ilmenite with sulphuric acid reaction. J Therm Anal Calorim 96:971977 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 18. Jabłoński, M 2008 Investigation of reaction products of sulphuric acid with ilmenite. J Therm Anal Calorim 93:717720 .

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jan 2021 0 0 0
Feb 2021 0 0 0
Mar 2021 0 0 0
Apr 2021 0 0 0
May 2021 1 0 0
Jun 2021 1 0 0
Jul 2021 0 0 0