Geopolymers
Inorganic polymeric new materials
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Magdalena Wirkowska
Magdalena Wirkowska
Faculty of Food Sciences, Warsaw University of Life Sciences, Ul. Nowoursynowska 166, 02-787, Warszawa, Poland
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Ewa Ostrowska-Ligęza
Ewa Ostrowska-Ligęza
Faculty of Food Sciences, Warsaw University of Life Sciences, Ul. Nowoursynowska 166, 02-787, Warszawa, Poland
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Agata Górska
Agata Górska
Faculty of Food Sciences, Warsaw University of Life Sciences, Ul. Nowoursynowska 166, 02-787, Warszawa, Poland
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Piotr Koczoń
Piotr Koczoń
Faculty of Food Sciences, Warsaw University of Life Sciences, Ul. Nowoursynowska 166, 02-787, Warszawa, Poland
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Abstract
The aim of this research was to analyse composition, fatty acids distribution and oxidative stability of fats extracted from four samples of baby formulas. The fats were oxidized in a differential scanning calorimeter (DSC) under polythermal (dynamic) conditions and at normal pressure. The DSC experiments were carried out in an oxygen flow atmosphere using different, linearly programmed, heating rates in the range of 4–12.5 °C/min. The extrapolated onset temperatures were determined using DSC exotherms and used for the assessment of the thermal oxidative stabilities of the samples. Activation energies (Ea), pre-exponential factors (Z) and reaction rate constants (k) for oil oxidation under DSC conditions were calculated using the Ozawa–Flynn–Wall method and the Arrhenius equation. The melting characteristics of the studied fats were obtained. The fats extracted from the agglomerated samples with higher onset temperatures were more stable than the fats extracted from the initial samples of baby formulas.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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