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  • 1 Department of Chemical Thermodynamics and Kinetics, Saint Petersburg State University, Universitetskiy pr., 26, Saint Petersburg, Russia, 198504
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Abstract

The behavior in aqueous solutions of the two types of layered perovskite-like structures, NaLnTiO4 titanates (Ln = Nd, La) belonging to the family of Ruddlesden–Popper phases and ANdTa2O7 tantalates (A = Na, Cs, H) belonging to the family of Dion–Jacobson phases, has been studied by means of thermogravimetric analysis and powder X-ray diffraction. In the case of NaLnTiO4 compounds, the substitution of protons for sodium cations and the water intercalation into the interlayer space of the crystal structure were observed and proton-containing layered oxides with general formula HxNa1−xLnTiO4·yH2O (0.63 < x < 1, 0 < y < 0.74) have been obtained. Investigation on the hydration in layered tantalates ANdTa2O7 (A = H, Na, Cs) showed that NaNdTa2O7 and HNdTa2O7 form compounds intercalated by water molecules. Two steps of water intercalation were observed for NaNdTa2O7 and HNdTa2O7. Stable hydrated compounds HNdTa2O7·0.84H2O, NaNdTa2O7·0.60H2O, and NaNdTa2O7·1.35H2O were synthesized.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)