Geopolymers
Inorganic polymeric new materials
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Jo Nakayama
Jo Nakayama
Graduate School of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa, 240-8501, Japan
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Atsumi Miyake
Atsumi Miyake
Graduate School of Environment and Information Sciences, Yokohama National University, 79-7 Tokiwadai, Hodogaya-ku, Yokohama, Kanagawa, 240-8501, Japan
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Abstract
The reuse and recycling of biomass materials can minimize the environmental impact of society, and can help create a sustainable community. Although cellulosic biomass from demolished buildings is a promising resource for recycling, contaminants, such as wood preservatives that likely contain metal oxides, are found in recycled wood dust. These oxides could act as catalysts for the oxidation of organic materials, resulting in spontaneous ignition of large piles of recycled wood dust. Copper(II) oxide (CuO) is major component in wood preservative and plays a catalytic role in the oxidation of cellulose, which could cause spontaneous ignition. The present study focused on the influence of CuO on oxidation of cellulose. The exothermal behavior and mass loss of cellulose/CuO mixtures were investigated. Changes in exothermal behavior and mass loss with an increasing amount of CuO were measured by differential scanning calorimetry and thermogravimetry. In addition, kinetics and spectroanalysis were conducted to determine the catalytic effect of CuO on oxidation of cellulose and help determine the oxidation model of cellulose upon addition of CuO. Results revealed a change in exothermal behavior and increase in mass loss with increasing amounts of CuO. In addition, CuO had a catalytic effect on the oxidation of cellulose, which helped determine the oxidation model of cellulose upon addition of CuO.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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