Geopolymers
Inorganic polymeric new materials
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A. Saponar
A. Saponar
Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University, 400294, Cluj-Napoca, Romania
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E.-J. Popovici
E.-J. Popovici
Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University, 400294, Cluj-Napoca, Romania
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I. Perhaita
I. Perhaita
Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University, 400294, Cluj-Napoca, Romania
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G. Nemes
G. Nemes
Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, 400084, Cluj-Napoca, Romania
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A.-I. Cadis
A.-I. Cadis
Raluca Ripan Institute for Research in Chemistry, Babes Bolyai University, 400294, Cluj-Napoca, Romania
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Abstract
The thermal behaviour of three ester derivatives of p-tert-butyl calix[n]arene (n = 4, 6 and 8) in comparison with the parent calixarene was investigated by means of the thermogravimetric (TG) and differential thermogravimetic (DTG) analysis and differential scanning calorimetry (DSC). The thermal stability domains, the composition of the pyrolysis products and the thermal effects, were determined on the basis of TG, DTG and DSC plots registered in nitrogen flow. Attempts to analyse the evolved gases by TG-FTIR coupling were also performed. It was demonstrated that the stability of the calix[n]arene derivatives depends on both the size of the hydrophobic cavity and number of the substituting groups grafted on the calix[n]arene skeleton.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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