Geopolymers
Inorganic polymeric new materials
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M. V. Šiljegović
M. V. Šiljegović
Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia
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S. R. Lukić-Petrović
S. R. Lukić-Petrović
Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia
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G. R. Štrbac
G. R. Štrbac
Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia
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D. M. Petrović
D. M. Petrović
Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia
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Abstract
Kinetic analysis of the crystallization process in Bi4(As2S3)96 and Bi6(As2S3)94 glasses was performed based on DSC curves recorded under non-isothermal measurement conditions. Samples were thermally treated at different heating rates in the temperature range 300–770 K. The activation energy of crystallization E and the pre-exponential factor K0 are determined by the Kissinger method and the characteristic crystallization parameters m and n of investigated glasses by the Matusita method. For both crystallization processes the glass with 4 at.% of Bi is characterized by the mechanism of volume nucleation, which is manifested in the form of two-dimensional growth at the first crystallization process, and as three-dimensional at the second one. On the other hand, in the sample with 6 at.% Bi, the average value of the parameter m is close to one, which indicates one-dimensional crystal growth. Compatibility of the values of the parameters m and n suggests that this sample has a large number of crystallization centers, which do not increase significantly during the thermal treatment.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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