Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 110: Issue 1
Kinetic analysis of the crystallization processes in the glasses of the Bi–As–S system
Authors:
M. V. Šiljegović Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia

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S. R. Lukić-Petrović Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia

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G. R. Štrbac Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia

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D. M. Petrović Department of Physics, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 4, 21000, Novi Sad, Serbia

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Pages:
379–384
Online Publication Date:
18 Mar 2012
Publication Date:
01 Oct 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-012-2353-z
Keywords (English):
Chalcogenide glasses; Thermal properties; Crystallization; Crystal growth
Restricted access

Abstract

Kinetic analysis of the crystallization process in Bi4(As2S3)96 and Bi6(As2S3)94 glasses was performed based on DSC curves recorded under non-isothermal measurement conditions. Samples were thermally treated at different heating rates in the temperature range 300–770 K. The activation energy of crystallization E and the pre-exponential factor K0 are determined by the Kissinger method and the characteristic crystallization parameters m and n of investigated glasses by the Matusita method. For both crystallization processes the glass with 4 at.% of Bi is characterized by the mechanism of volume nucleation, which is manifested in the form of two-dimensional growth at the first crystallization process, and as three-dimensional at the second one. On the other hand, in the sample with 6 at.% Bi, the average value of the parameter m is close to one, which indicates one-dimensional crystal growth. Compatibility of the values of the parameters m and n suggests that this sample has a large number of crystallization centers, which do not increase significantly during the thermal treatment.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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