Geopolymers
Inorganic polymeric new materials
Author:
Authors:
,
, and
Christian Siewert
Christian Siewert
Faculty of Landscape Management, University of Applied Sciences Dresden, Pillnitzer Platz 2, 01326, Dresden, Germany
Search for other papers by Christian Siewert in
Current site
Google Scholar
PubMed
Search for other papers by Christian Siewert in
Current site
Google Scholar
PubMed
Michael Scott Demyan
Michael Scott Demyan
Institute of Plant Production and Agroecology in the Tropics and Subtropics, University of Hohenheim, Garbenstrasse 13, 70593, Stuttgart, Germany
Search for other papers by Michael Scott Demyan in
Current site
Google Scholar
PubMed
Search for other papers by Michael Scott Demyan in
Current site
Google Scholar
PubMed
Jiří Kučerík
Jiří Kučerík
Faculty of Chemistry, Brno University of Technology, Purkyňova 118, 61200, Brno, Czech Republic scott_demyan@yahoo.com
Institute of Environmental Sciences, University of Koblenz-Landau, Fortstrasse 7, 768 29, Landau, Germany kucerik@uni-landau.de
Search for other papers by Jiří Kučerík in
Current site
Google Scholar
PubMed
Institute of Environmental Sciences, University of Koblenz-Landau, Fortstrasse 7, 768 29, Landau, Germany kucerik@uni-landau.de
Search for other papers by Jiří Kučerík in
Current site
Google Scholar
PubMed
Abstract
Biological transformation of organic matter in soil is a crucial factor affecting the global carbon cycle. In order to understand these complex processes, soils must be investigated by a combination of various methods. This study compares the dynamics of biological mineralization of soil organic matter (SOM) determined via CO2 evolution during an 80-day laboratory incubation with their thermo-oxidative stability determined by thermogravimetry (TG). Thirty-three soil samples, originating from a wide range of geological and vegetation conditions from various German national parks were studied. The results showed a correlation between the amount and rate of respired CO2 and thermal mass losses of air-dried, conditioned soils occurring around 100 °C with linear coefficients of determination up to R2 = 0.85. Further, correlation of soil respiration with thermal mass losses around 260 °C confirmed previous observations. The comparison of TG profiles from incubated and non-incubated soils underlined the importance of thermal mass losses in these two temperature intervals. Incubated soils had reduced thermal mass losses above 240 °C and conversely an increased mass loss at 100–120 °C. Furthermore, the accurate determination of soil properties by TG such as soil organic carbon content was confirmed, and it was shown that it can be applied to a wider range of carbon contents as was previously thought. It was concluded that results of thermal analysis could be a helpful starting point for estimation of soil respiration and for development of methods revealing processes in soils.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1. Bastida, F, Zsolnay, A, Hernández, T, García, C 2008 Past, present and future of soil quality indices: a biological perspective. Geoderma 147:159–171 .
-
2. Minasny, B, McBratney, AB, Salvador-Blanes, S 2008 Quantitative models for pedogenesis—a review. Geoderma 144:140–157 .
-
3. Barros, N, Gallego, M, Feijóo, S 2007 Calorimetry and soil. Thermochim Acta 458:11–17 .
-
4. Barros, N, Gallego, M, Feijóo, S 2007 Sensitivity of calorimetric indicators of soil microbial activity. Thermochim Acta 458:18–22 .
-
5. Siewert, C 2001 Investigation of the thermal and biological stability of soil organic matter Shaker-Verlag Aachen.
-
6. Siewert, C 2004 Rapid screening of soil properties using thermogravimetry. Soil Sci Soc Am J 68:1656–1661 .
-
7. Plante, AF, Fernández, JM, Leifeld, J 2009 Application of thermal analysis techniques in soil science. Geoderma 153:1–10 .
-
8. Zhang, L, LeBoeuf, E, Xing, B 2007 Thermal analytical investigation of biopolymers and humic- and carbonaceous-based soil and sediment organic matter. Environ Sci Technol 41:4888–4894 .
-
9. Šmejkalová, D, Piccolo, A, Spiteller, M 2006 Oligomerization of humic phenolic monomers by oxidative coupling under biomimetic catalysis. Environ Sci Technol 40:6955–6962 .
-
10. White, RE 1987 Introduction to the principles and practice of soil science 2 Blackwell Oxford.
-
11. Dyal, RS, Drosdoff, M 1941 Determining organic matter in Florida soils. Soil Sci Soc Florida Proc 3:91–96.
-
12. Gaál, F, Szöllösy, I, Arnold, M, Paulik, F 1994 Determination of the organic matter, metal carbonate and mobile water in soils. Simultaneous TG, DTG, DTA and EGA techniques. J Therm Anal Cal 42:1007–1016 .
-
13. Kristensen, E 1990 Characterization of biogenic organic matter by stepwise thermogravimetry (STG). Biogeochemistry 9:135–159 .
-
14. Petrosyan, GP, Aranbaev, MP, Grigoryan, FA 1974 Derivatographic investigation of the mineralogical composition of fine-grained fractions of humus of arid zone soils. Therm Anal 2:745–753.
-
15. DIN 18128. German Standard. Untersuchung von Bodenproben: Bestimmung des Glühverlusts. 1990.
-
16. Plante, AF, Fernández, JM, Haddix, ML, Steinweg, JM, Conant, RT 2011 Biological, chemical and thermal indices of soil organic matter stability in four grassland soils. Soil Biol Biochem 43:1051–1058 .
-
17. Potts, M 1994 Desiccation tolerance of prokaryotes. Microbiol Rev 58:755–805.
-
18. Uren NC . Types, amounts, and possible functions of compounds released into the rhizosphere by soil-grown plants. In Pinton et al., editors. The rhizosphere: biochemistry and organic substances at the soil-plant interface. Taylor and Francis group; 2007. p. 23–72.
-
19. Lopez-Capel, E, Sohi, SP, Gaunt, JL, Manning, DAC 2005 Use of thermogravimetry-differential scanning calorimetry to characterize modelable soil organic matter fractions. Soil Sci Soc Am J 69:136–140 .
-
20. Plante, AF, Pernes, M, Chenu, C 2005 Changes in clay-associated organic matter quality in a C depletion sequence as measured by differential thermal analyses. Geoderma 129:186–199 .
-
21. Jaeger, F, Grohmann, E, Schaumann, GE 2006 1H NMR relaxometry in natural humous soil samples: insight in microbial effects on relaxation time distributions. Plant Soil 280:209–222 .
-
22. Hurrass, J, Schaumann, GE 2007 Hydration kinetics of wettable and water-repellent soils. Soil Sci Soc Am J 71:280–288 .
-
23. Rotaru, A, Gosa, M 2009 Computational thermal and kinetic analysis. J Therm Anal Cal 97:421–426 .
-
24. Simon, P 2009 Material stability predictions applying a new non-Arrhenian temperature function. J Therm Anal Cal 97:391–396 .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Jun 2024 | 10 | 1 | 2 |
| Jul 2024 | 46 | 0 | 0 |
| Aug 2024 | 21 | 1 | 1 |
| Sep 2024 | 36 | 0 | 0 |
| Oct 2024 | 220 | 0 | 0 |
| Nov 2024 | 89 | 0 | 0 |
| Dec 2024 | 10 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory