View More View Less
  • 1 Department of Chemistry, Himachal Pradesh University, Summer Hill, Shimla 171005, India
Restricted access

Abstract

The thermal decomposition behaviours of oxovanadium(IV)hydroxamate complexes of composition [VO(Q)2−n(HL1,2)n]: [VO(C9H6ON)(C6H4(OH)(CO)NHO)] (I), [VO(C6H4(OH)(CO)NHO)2] (II), [VO(C9H6ON)(C6H4(OH)(5-Cl)(CO)NHO)] (III), and [VO(C6H4(OH)(5-Cl)(CO)NHO)2] (IV) (where Q = C9H6NO 8-hydroxyquinolinate ion; HL1 = [C6H4(OH)CONHO] salicylhydroxamate ion; HL2 = [C6H3(OH)(5-Cl)CONHO] 5-chlorosalicylhydroxamate ion; n = 1 and 2), which are synthesised by the reactions of [VO(Q)2] with predetermined molar ratios of potassium salicylhydroxamate and potassium 5-chlorosalicylhydroxamate in THF + MeOH solvent medium, have been studied by TG and DTA techniques. Thermograms indicate that complexes (I) and (III) undergo single-step decomposition, while complexes (II) and (IV) decompose in two steps to yield VO(HL1,2) as the likely intermediate and VO2 as the ultimate product of decomposition. The formation of VO2 has been authenticated by IR and XRD studies. From the initial decomposition temperatures, the order of thermal stabilities for the complexes has been inferred as III > I > II > IV.

  • 1.

    Pang, SYM, Tristram, S, Brown, S. 2011. Salicylhydroxamic acid inhibits the growth of Candida albicans. Inter J Bio Life Sci. 7:4046.

    • Search Google Scholar
    • Export Citation
  • 2.

    O'Brien, EC S Le Roy Levaillain, J, Fitzgerald, DJ, Nolan, KB. 1997. Metal complexes of salicylhydroxamic acid and O-acetylsalicylhydroxamic acid. Inorg Chim Acta. 266:117120 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3.

    Dankwardt, SM, Billedeau, RJ, Lawley, LM, Abbot, SC, Martin, RL, Chan, CS HE Van Wart Walker, KAM. 2000. Solid-phase synthesis of di- and tripeptidic hydroxamic acids as inhibitors of procollagen C-proteinase. Bioorg Med Chem Lett. 10:25132516 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4.

    Rice, CP, Park, YB, Adam, F, Abdul-baki, AA, Teasdale, JR. 2005. Hydroxamic acid content and toxicity of rye at selected growth stages. J Chem Eco. 31:18871905 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5.

    Holms J , Mast K, Marcotte P, Elmore I, Li J, Pease L. Glaser K, Morgan D, Michaelides, M, Davidsen S. Discovery of selective hydroxamic acid inhibitors of tumor necrosis factor-[alpha] conerting enzyme. Bioorg Med Chem Lett. 2000;11: 290710.

    • Search Google Scholar
    • Export Citation
  • 6.

    González-Baró, AC, Baran, EJ. 2001. Synthesis and spectroscopic behavior of some oxovanadium(IV) and oxovanadium(V) complexes of 7-iodo-8-hydroxyquinoline-5-sulfonate. J Braz Chem Soc. 12:208214 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7.

    Baran, EJ. 2000. Oxovanadium(IV) and oxovanadium(V) complexes relevant to biological systems. J Inorg Biochem. 80:110 .

  • 8.

    González-Baró, AC, Baran, EJ. 1997. Oxovanadium(IV) complexes of halogenated oxines. Monatsh Chem. 128:323335 .

  • 9.

    Shen, AY, Wu, SN, Chiu, CT. 1999. Synthesis and cytotoxicity evaluation of some 8-hydroxyquinoline derivatives. J Pharm Pharmacol. 51:543548 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 10.

    Aureliano, M, Crans, DC. 2009. Decavanadate (V10O28 6−) and oxovanadates: oxometalates with many biological activities. J Inorg Biochem. 103:536546 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11.

    Wang, Q, Liu, TT, Fu, Y, Wang, K, Yang, XG. 2010. Vanadium compounds discriminate hepatoma and normal hepatic cells by differential regulation of reactive oxygen species. J Biol Inorg Chem. 15:10871097 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12.

    Badea, M, Olar, R, Uivarosi, V, Marinescu, D, Aldea, V. 2012. Synthesis and characterization of some vanadyl complexes with flavonoid derivatives as potential insulin-mimetic agents. J Therm Anal Calorim. 107:279285 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13.

    Zhao, H, Bennici, S, Shen, J, Auroux, A. 2009. Surface and catalytic properties of V2O5–TiO2/SO4 2− catalysts for the selective oxidation of methanol prepared by various methods. J Mol Catal A Chem. 309:2834 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 14.

    Sharma, N, Kumar, V, Sharma, R, Kumari, M, Kanwar, SS. 2011. Coordination compounds of hydroxamatooxovanadium(IV) complexes with nitrogenous bases and their antimicrobial activities. Bull Chem Soc Jpn. 84:855861 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 15.

    Sharma, N, Kumari, M, Kumar, V, Chaudhry, SC, Kanwar, SS. 2010. Synthesis, characterization and antimicrobial activity of oxovanadium(IV)hydroxamate complexes. J Coord Chem. 63:19401950 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 16.

    Sharma N , Kanwar SS, Gupta R, Kumari L, Sharma R. Reactions of bis(8-hydroxyquinolato)oxovanadium(IV) with hydroxamate ligands: a route providing mixed ligand and quinolinato free vanadium(IV) complexes. Bull Chem Soc Jpn. (in Press).

    • Search Google Scholar
    • Export Citation
  • 17.

    Sharma, N, Kumari, M, Sharma, R. 2012. Thermoanalytical studies of oxovanadium(IV)hydroxamate complexes. J Therm Anal Calorim. 107:225229 .

  • 18.

    Sharma N , Guleria A, Pathania A, Sharma M, Rekha P, Arora S, Sharma R. Thermal behaviour of bis(hydroxamato)oxovanadium(IV) complexes. Thermans. 2012;18: 31214.

    • Search Google Scholar
    • Export Citation
  • 19.

    Singh, RK, Yadav, A, Narayan, A, Chandra, M, Verma, RK. 2012. Thermal, XRD and magnetization studies on ZnAl2O4 and NiAl2O4 spinels, synthesized by citrate precursor method and annealed at 450 and 650 °C. J Therm Anal Calorim. 107:205210 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 20.

    Singh, RK, Yadav, A, Narayan, A, Singh, AK, Verma, L, Verma, RK. 2012. Thermal, structural and magnetic studies on chromite spinel synthesized using citrate precursor method and annealed at 450 and 650 °C. J Therm Anal Calorim. 107:197204 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 21.

    Vlaev, LT, Georgieva, VG, Genieva, SD. 2007. Products and kinetics of non-isothermal decomposition of vanadium(iv) oxide compounds. J Therm Anal Calorim. 88:805812 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 22.

    Ahamad, MN, Vaish, R, Varma, KBR. 2011. Calorimetric studies on 2TeO2–V2O5 glasses. J Therm Anal Calorim. 105:239243 .

  • 23.

    Wang, H, Yi, X, Chen, S, Fu, X. 2005. Fabrication of vanadium oxide micro-optical switches. Sens Actuator A Phys. 122:108112 .

  • 24.

    Xiao, D, Kim, KW, Zavada, JM. 2007. Imaging properties of a metallic photonic crystal. J Appl Phys. 101:11310511131055.

  • 25.

    Liu, YM, Cao, Y, Yi, N, Feng, WL, Dai, WL, Yan, SR, He, HY, Fan, KN. 2004. Vanadium oxide supported on mesoporous SBA-15 as highly selective catalysts in the oxidative dehydrogenation of propane. J Catal. 224:417428 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 26.

    Li, Y, Huang, Z, Rong, S. 2006. A vanadium oxide nanotube-based nitric oxide gas sensor. Sens Mater. 18:241249.

  • 27.

    Pasquali, M, Landi, A, Floriani, C. 1979. (Pyridine)bis(8-quinolinato)oxovanadium(IV): a free- radical- like metal center in reactions with dioxygen, p-benzoquinone, and aromatic nitroso compounds. I Inorg Chem. 18:23972400 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 28.

    Hauser, CR, Renfrow, WB. 1953. Benzohydroxamic acid. J Org Synth. 2:67.

  • 29.

    Botto, IL, Vassallo, MB, Baran, EJ, Minelli, G. 1997. IR spectra of VO2 and V2O3. Mater Chem Phys. 50:267270 .

  • 30.

    Mlyuka, NR, Niklasson, GA, Granqvist, CG. 2009. Thermochromic VO2-based multilayer films with enhanced luminous transmittance and solar modulation. Phys Status Solidif A. 206:21552160 .

    • Crossref
    • Search Google Scholar
    • Export Citation

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

For subscription options, please visit the website of Springer.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)