Authors:
A. Iddaoudi Laboratory of Thermodynamics and Energy (L.T.E), Faculty of Science, University Ibn Zohr, B. P. 8106, Agadir, Morocco

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N. Selhaoui Laboratory of Thermodynamics and Energy (L.T.E), Faculty of Science, University Ibn Zohr, B. P. 8106, Agadir, Morocco

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M. Ait Amar Laboratory of Thermodynamics and Energy (L.T.E), Faculty of Science, University Ibn Zohr, B. P. 8106, Agadir, Morocco

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K. Mahdouk Laboratory of Thermodynamics and Energy (L.T.E), Faculty of Science, University Ibn Zohr, B. P. 8106, Agadir, Morocco

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A. Aharoune Laboratory of Thermodynamics and Energy (L.T.E), Faculty of Science, University Ibn Zohr, B. P. 8106, Agadir, Morocco

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L. Bouirden Laboratory of Thermodynamics and Energy (L.T.E), Faculty of Science, University Ibn Zohr, B. P. 8106, Agadir, Morocco

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Abstract

The thermodynamic modeling of the Lu–Pb binary system was carried out with the help of CALPHAD (Calculation of PHAse Diagram) method. The liquid phase has been described with the association solution model with “Lu5Pb3” as an associated complex. Lu5Pb3, α-Lu5Pb4, β-Lu5Pb4, Lu6Pb5, and LuPb2 have been treated as stoichiometric compounds, while a sublattice model has been used for the description of the HCP phase. The calculations based on the thermodynamic modeling are in good agreement with the phase diagram data and experimental thermodynamic values.

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    Idbenali, M, Servant, C, Selhaoui, N, Bouirden, L. 2009. Thermodynamic description Pb–Yb binary system. Calphad. 33:570575 .

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    Idbenali, M, Servant, C, Selhaoui, N, Bouirden, L. 2008. A thermodynamic reassessment of the Ca–Pb system. Calphad. 32:6473 .

  • 3.

    Idbenali, M, Servant, C, Selhaoui, N, Bouirden, L. 2007. A thermodynamic modelling of the Ba–Pb system. Calphad. 31:479489 .

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    Dinsdale, AT. 1991. SGTE data for pure elements. Calphad. 15:317425 .

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    Sommer, F. 1982. Association model for the description of the thermodynamic functions of liquid alloys. I.—Basic concepts. Zeitschrift fur Metallkunde. 73:7276.

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    Redlich, O, Kister, A. 1948. Algebraic representation of thermodynamic properties and the classification of solutions. Ind Eng Chem. 40:345348 .

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    Sundman, B, Jansson, B, Andersson, JO. 1985. The thermo-calc databank system. Calphad. 9:153190 .

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    Jansson B . Ph.D. Thesis, Division of Physical Metallurgy, Royal Institute of Technology, Stockholm, Sweden, 1984.

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    Stein, F, Palm, M, Sauthoff, G. 2005. Structure and stability of Laves phases. Part II-Structure type variations in binary and ternary system. Intermetallics. 13:10561074 .

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    Chen, SL, Daniel, S, Zhang, F, Chang, YA, Oates, WA, Schmid-Fetzer, R. 2001. On the calculation of multicomponent stable phase diagrams. J Phase Equilib. 22:373378 .

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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