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  • 1 Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran
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Abstract

Thirty-four nano-basket derivatives of di-ionizable calix[4]arene conformers in nine scaffolds bearing two pendant groups of N-(R)-sulfonyl carboxamides were synthesized and examined using isothermal titration calorimetry. The binding mechanisms of synthesized conformers toward alkali metal cations were evaluated and two main interactions were assessed including cation–π interaction between alkali metal and the aromatic unit of conformer as well as the strong binding ion–dipole interaction between nitrogen atoms in the pendant groups and alkali cation. The ITC data revealed that the bindings of cone and partial-cone conformers toward alkali metal cations exhibited one-step mechanism, while both 1,2 alternate conformer bounds the alkali metal cations in a two-step mechanism.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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