Geopolymers
Inorganic polymeric new materials
Author:
Authors:
,
,
, and
Dursun Ali Köse
Dursun Ali Köse
Department of Chemistry, Faculty of Arts and Sciences, Hitit University, 19000, Çorum, Turkey
Search for other papers by Dursun Ali Köse in
Current site
Google Scholar
PubMed
Search for other papers by Dursun Ali Köse in
Current site
Google Scholar
PubMed
Hacali Necefoğlu
Hacali Necefoğlu
Department of Chemistry, Faculty of Arts and Sciences, Kafkas University, 36100, Kars, Turkey
Search for other papers by Hacali Necefoğlu in
Current site
Google Scholar
PubMed
Search for other papers by Hacali Necefoğlu in
Current site
Google Scholar
PubMed
Onur Şahin
Onur Şahin
Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey
Search for other papers by Onur Şahin in
Current site
Google Scholar
PubMed
Search for other papers by Onur Şahin in
Current site
Google Scholar
PubMed
Orhan Büyükgüngör
Orhan Büyükgüngör
Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139, Kurupelit, Samsun, Turkey
Search for other papers by Orhan Büyükgüngör in
Current site
Google Scholar
PubMed
Search for other papers by Orhan Büyükgüngör in
Current site
Google Scholar
PubMed
Abstract
The mixed-ligand 3-hydroxybenzoic acid complex of Zn(II) with nicotinamide and N,N-diethylnicotinamide were synthesized and characterized (colorless single crystals, [Zn(3-hba)2(H2O)2(na)2] and [Zn(3-hba)2(H2O)2(dena)2]). The chemical, FT-IR, thermal, mass spectral analyses, and X-ray data results revealed that both of the compounds contain two water molecules, two 3-hydroxybenzoate (3-hba) and two nicotinamide (na) or two N,N-diethylnicotinamide (dena) ligands per formula unit. 3-hba and na or dena ligands bind to the Zn(II) ion monodentately through their acidic oxygen and pyridinic nitrogen atoms, respectively. The coordination of metal atoms are completed by two molecules of aqua ligands. The charge balance of complexes is accommodated by two molecules of 3-hba ions. The unit cell has two molecules coordination molecules and each of them was as settled to four surfaces of unit cell cage in na complex. There is one mole molecule that was occupied to center of unit cell cage in dena complex. The two dimensional network structure of the complex is like a hexagonal for na and square plane for dena complexes. The thermal decomposition takes place in three steps; first, dehydration of the two aqua ligands, second, elimination of the two nicotinamide ligands, finally, burning of the two benzoate ion ligands.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1.
Emery, P, Kong, SX, Ehrich, EW, Watson, DJ, Towheed, TE. 2002. Dose-effect relationships of nonsteroidal anti-inflammatory drugs: a literature review. Clin Ther. 24:1225–1291 .
-
2.
Sorenson JRJ . In: Sigel H, editor. Metal ions in biological systems. New York: Marcel Dekker; 1982.
-
3.
Dendrinou-Samara, C, Tsotsou, G, Ekateriniadou, LV, Kortsaris, AH, Raptopoulou, CP, Terzis, A, Kyriakidis, DA, Kessissoglou, DP. 1998. Anti-inflammatory drugs interacting with Zn(II), Cd(II) and Pt(II) metal ions. JInorg Biochem. 71:171–179 .
-
4.
Stuhlmeier, KM, Li, H, Kao, JJ. 1999. Ibuprofen: new explanation for an old phenomenon. Biochem Pharmacol. 5:313–320 .
-
5.
Rice-Evans, CA, Miller, NJ, Paganga, G. 1996. Structure antioxidant-activity relationships of flavonoids and phenolic acids. Free Radical Biol Med. 20:933–956 .
-
6.
Hossaini, A, Larsen, JJ, Larsen, JC. 2000. Lack of oestrogenic effects of food preservatives (parabens) in uterotrophic assays. Food Chem Toxicol. 38 4 319–323 .
-
7.
Diehl, KB. 1996. Topical antifungal agents: an update. Am Fam Physician. 54:1687–1692.
-
8.
Rastogi, SC, Lepoittevin, JP, Johansen, JD, Frosch, PJ, Menne, T, Bruze, M, Dreier, B, Andersen, KE, White, IR. 1998. Fragrances and other materials in deodorants: search for potentially sensitizing molecules using combined GC-MS and structure activity relationship (SAR) analysis. Contact Dermatitis. 39:293–303 .
-
9.
Sainio, E, Kanerva, L. 1995. Contact allergens in toothpastes and a review of their hypersensitivity. Contact Dermatitis. 33:100–105 .
-
10.
Hanssen, M, Marsden, J. 1987 The new E for additives Thorsons Publishing, HarperCollins Publishers Wellinborough.
-
11.
Dock, LL, Floros, JD, Linton, RH. 2000. Heat inactivation of Escherichia coli O157:H7 in apple cider containing malic acid, sodium benzoate and potassium sorbate. J Food Prot. 63:1026–1031.
-
12.
Islam, M, Chen, J, Doyle, MP, Chinnan, MS. 2002. Control of Listeria monocytogenes on turkey frankfurters by generally-recognized-as-safe preservatives. J Food Prot. 65 9 1411–1416.
-
13.
Vallee, BL, Auld, DS. 1990. Zinc coordination, function, and structure of zinc enzymes and other proteins. Biochemistry. 29 24 5647–5659 .
-
14.
Kimura, E, Koike, T. 1997. Intrinsic properties of Zinc(II) ion pertinent to zinc enzymes. Adv Inorg Chem. 44:229–261 .
-
15.
Kaim, W, Schwederski, B. 1994 Bioinorganic chemistry: inorganic elements in the chemistry of life Wiley Chichester.
-
16.
Zelenak, V, Sabo, M, Massa, W, Llewellyn, P. 2004. Preparation, characterisation and crystal structure of two Zinc (II) benzoate complexes with pyridine-based ligands nicotinamide and methyl-3-pyridylcarbamate. Inorg Chim Acta. 357:2049–2059 .
-
17.
Korant, BD, Kauer, JC, Butterworth, BF. 1974. Zinc ions inhibit replication of rhinoviruses. Nature. 12 248–449 588–590 .
-
18.
E De Clercq 1997. Antiviral metal complexes. Metal-Based Drugs. 4:173–192 .
-
19.
Cunnane, SC. 1988 Zinc: clinical and biochemical significance CRC Press Boca Raton.
-
20.
Feucht, CL, Allen, BS, Chalker, DK Jr JG Smith 1980. Topical erythromycin with Zinc in acne. A double-blind controlled study. J Am Acad Dermatol. 3:483–491 .
-
21.
EJ van Hoogdalem 1998. Transdermal absorption of topical anti-acne agents in man; review of clinical pharmacokinetic data. J Eur Acad Dermatol Venereol. 11:S13–S19 .
-
22.
Kato, M, Muto, Y. 1988. Factors affecting the magnetic properties of dimeric Copper (II) complexes. Coord Chem Rev. 92:45–83 .
-
23.
Nagar, R. 1990. Syntheses, characterization, and microbial activity of some transition metal complexes involving potentially active O and N donor heterocyclic ligands. J Inorg Biochem. 40 4 349–356 .
-
24.
Cavigiolio, G, Benedetto, L, Boccaleri, E, Colangelo, D, Viano, I, Osella, D. 2000. Pt (II) complexes with different N-donor aromatic ligands for specific inhibition of telomerase. Inorg Chim Acta. 305:61–68 .
-
25.
Brühlmann, U, Hayon, E. 1974. One-electron redox reactions of water-soluble vitamins. I. Nicotinamide (vitamin B5) and related compounds. J Am Chem Soc. 96 19 6169–6175 .
-
26.
Köse, DA, Gökçe, G, Gökçe, S, Uzun, I. 2009. Bis(n,n-diethylnicotinamide)p-chlorobenzoate complexes of Ni(II), Zn(II) and Cd(II) synthesis and characterization. J Therm Anal Calorim. 95 1 247–251 .
-
27.
Köse, DA, Necefoglu, H, Icbudak, H. 2008. Synthesis and characterization of N,N diethylnicotinamide-acetylsalicylato complexes of Co(II), Ni(II), Cu(II), and Zn(II). J Coord Chem. 61 21 3508–3515 .
-
28.
Köse, DA, Necefoglu, H. 2008. Synthesis and characterization of bis (nicotinamide)m-hydroxybenzoate complexes of Co(II), Ni(II), Cu(II) and Zn(II). J Therm Anal Calorim. 93 2 509–514 .
-
29.
Sahin, O, Buyukgungor, O, Köse, DA, Necefoglu, H. 2007. trans-Diaquabis(3-hydroxybenzoato-kO1)bis(nicotinamide-kN1)copper(II). Acta Cryst. C63:m510–m512.
-
30.
Köse, DA, Kaya, A, Necefoglu, H. 2007. Synthesis and characterization of bis(N,N-Diethylnicotinamide) m-hydroxybenzoate complexes of Co(II), Ni(II), Cu(II) and Zn(II). Russ J Coord Chem. 33:422–427 .
-
31.
Motz, C, Roth, HP, Kirchgessner, M. 1995. Influence of bis(acetylsalicylato)-diaquo-zinc(II)-complex and acetylsalicylic acid on several parameters of the zinc status in growing rats. Trace Elem Electr. 12 1 1–6.
-
32.
Rzaczynska, Z, Kula, A, Sienkiewicz-Gromiuk, J, Szybiak, A. 2011. Synthesis, spectroscopic and thermal studies of 2,3-naphthale-nedicarboxylates of rare earth elements. J Therm Anal Calorim. 103:275–281 .
-
33.
Jabłonska-Wawrzycka A , Zienkiewicz M, Hodorowicz M, Rogala P, Barszcz B. Thermal behavior of manganese(II) complexes with pyridine-2,3-dicarboxylic acid Spectroscopic, X-ray, and magnetic studies. J Therm Anal Calorim. 2001. doi: .
-
34.
Barszcz, B, Masternak, J, Surga, W. 2010. Thermal properties of Ca(II) and Cd(II) complexes of pyridinedicarboxylates. Correlation with crystal structures. J Therm Anal Calorim. 101:633–639 .
-
35.
Devereux, M, Curran, M, McCann, M, Casey, RMT, McKee, V. 1999. Manganese(II) salicylate complexes as H2O2 disproportionation catalysts: X-ray crystal structure of [Mn(Hsal)2(bipy)]·H2O (H2sal = salicylic acid, bipy = 2,2′-bipyridine). Polyhedron. 15:2029–2033 .
-
36.
Köse DA . Synthesis and structural characterization of nicotinamide/diethylnicotinamide complexes with acetylsalicylates of Co(II), Ni(II), Cu(II) and Zn(II). M. Sc. Thesis; Kafkas University; Kars; 2000.
-
37.
Köse, DA, Zumreoglu-Karan, B, Unaleroglu, C, Sahin, O, Buyukgungor, O. 2006. Synthesis and characterization of transition metal-vitamin B13 complexes with a Co-vitamin. J Coord Chem. 59 18 2125–2133 .
-
38.
Köse, DA, Icbudak, H, Necefoğlu, H. 2007. Synthesis and characterization of the nicotinamide-acetylsalicylato complexes of Co(II), Ni(II), Cu(II) and Zn(II). Hacettepe J Bio Chem. 35 2 123–128.
-
39.
Köse, DA, Necefoglu, H, Sahin, O, Buyukgungor, O. 2011. Synthesis, spectral, thermal and structural study of monoaquabis(acetylsalicylato-κO)bis(nicotinamide-κN)copper(II). J Chem Crystallogr. 41:297–305 .
-
40.
Hökelek, T, Necefoğlu, H. 1997. Diaquabis(N,N-diethylnicotinamide-N)bis(2-hydroxybenzoato-O) cobalt(II). Acta Cryst. C53:187–189.
-
41.
Necefoğlu, H, Clegg, W, Scott, AJ. 2001. Diaquabis(N,N-diethylnicotinamide)bis(2-hydroxy-benzoato)zinc(II). Acta Cryst. E57:m462–m464.
-
42.
Sheldrick, GM. 2008. A short history of SHELX. Acta Cryst. A64:112–114.
-
43.
Farrugia, LJ. 1999. WinGX suite for small-molecule single-crystal crystallography. J Apply Cryst. 32:837–838 .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Apr 2024 | 51 | 0 | 0 |
| May 2024 | 30 | 0 | 0 |
| Jun 2024 | 18 | 0 | 0 |
| Jul 2024 | 10 | 0 | 0 |
| Aug 2024 | 18 | 0 | 0 |
| Sep 2024 | 46 | 0 | 0 |
| Oct 2024 | 26 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory