Synthesis, characterizations, and thermal behavior of Na2[MoO(O2)2(C2O4)] was studied. The thermally induced events will be observed by comparing the FT-IR spectra of the initial compound and of the char at 300 and 500 °C. The TG data were obtained at different heating rates: β = 2.5, 4, 5, and 10 °C min−1 in air and nitrogen (50 mL min−1), and the TG/DTG data were processed with the following methods: Friedman, Flynn–Wall–Ozawa, and modified NPK method.
Passoni, LC, Siddiqui, MRH, Steiner, A, Kozhevnikov, IV. 2000. Niobium peroxo compounds as catalysts for liquid-phase oxidation with hydrogen peroxide. J Mol Catal A. 15:103.
H Mimoun S Patai eds. 1983 The chemistry of peroxides Wiley New York.
Bayot, D, Tinant, B, Devillers, M. 2004. Spectroscopic and structural characterizations of ammonium peroxo-carboxylato molydate (VI) complexes. Inorg Chim Acta. 357:809–816 .
Dengel, AC, Griffith, WP, Powell, RD, Skapski, AC. 1987. Studies on Transition-metal Peroxo Complexes. Part 7: +molybdenum (VI) and tungsten (vi) carboxylato peroxo complexes, and the X-ray crystal structure of K2[MoO(O2)2 (glyc)] H2O. J Chem Soc Dalton Trans. 5:991–995 .
Sheikh, HN, Hussain, A, Kalsotra, BL. 2006. Synthesis and characterization of some oxodiperoxo molybdenum (VI) complexes of morpholinomethyl urea and related ligands. Russ J Inorg Chem. 51 5 724–727 .
Brown, ME, Maciejewski, M, Vyazovkin, S, Nomen, R, Sempere, J, Burnham, A et al. 2000. Computational aspects of kinetic analysis: part A: the ICTAC kinetics project-data, methods and results. Thermochim Acta. 355:125–143 .
Friedman, HL. 1965. Kinetics of thermal degradation of char-foaming plastics from thermogravimetry: application to a phenolic resin. J Polym Sci. 6C:183–195.
Flynn, JH, Wall, LA. 1966. A quick, direct method for the determination of activation energy from thermogravimetric data. Polym Lett. 4:323–328 .
Ozawa, T. 1965. A new method of analyzing thermogravimetric data. Bull Chem Soc Jpn. 38:1881–1886 .
Vlase, T, Vlase, G, Birta, N, Doca, N. 2007. Comparative results of kinetic data obtained with different methods for complex decomposition steps. J Therm Anal Calorim. 88:631–635 .
Vlase, G, Vlase, T, Doca, N. 2008. Thermal behavior of some phenitoine pharmaceuticals. J Therm Anal Calorim. 92:259–262 .
Birta, N, Doca, N, Vlase, G, Vlase, T. 2008. Kinetic of sorbitol decomposition under non-isothermal conditions. J Therm Anal Calorim. 92:635–638 .
Vlase, T, Doca, N, Vlase, G, Bolcu, C, Borcan, F. 2008. Kinetics of non-isothermal decomposition of three IRGANOX-type antioxidants. J Therm Anal Calorim. 92:15–18 .
Fuliaş, A, Vlase, G, Vlase, T, Tiţa, B, Tiţa, D, Doca, N. 2010. Thermal study of cefoperazone monohydrate. Rev Roum Chem. 55 8 481–486.
Fuliaş, A, Vlase, T, Vlase, G, Doca, N. 2010. Thermal behaviour of cephalexin in different mixtures. J Therm Anal Calorim. 99 3 987–992 .
Vlase, T, Vlase, G, Doca, N, Bolcu, C. 2005. Processing of non-isothermal TG data. Comparative kinetic analysis with NPK method. J Therm Anal Calorim. 80:59–64 .
Wall ME . Singular value decomposition and principal component analysis. In: Berrar DP, Dubitzky W, Granzow M, editors. A practical approach to microarray data analysis, vol. 9. Norwel: Kluwer; 2003. p. 91–109. LANL LA-UR-02.
Śestak, J, Berggren, G. 1971. Study of the kinetics of the mechanism of solid-state reactions at increasing temperatures. Thermochim Acta. 3:1–12 .