Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 110: Issue 3
Thermal behavior, non-isothermal decomposition reaction kinetics and thermal-safety evaluation on N-2,4-dinitrophenyl-3,3-dinitroazetidine under two different pressures
Authors:
B. Yan School of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an 710069, Shaanxi, China
School of Chemistry and Chemical Engineering, Yulin University, Yulin 719000, Shaanxi, China

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H. X. Ma School of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an 710069, Shaanxi, China

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N. N. Zhao School of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an 710069, Shaanxi, China

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T. Mai School of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an 710069, Shaanxi, China

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J. R. Song School of Chemical Engineering/Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an 710069, Shaanxi, China
Department of Conservation Technology, The Palace Museum, Beijing 100009, China

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F. Q. Zhao Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, Shaanxi, China

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R. Z. Hu Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, Shaanxi, China

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Pages:
1253–1257
Online Publication Date:
10 Dec 2011
Publication Date:
01 Dec 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-011-2053-0
Keywords:
N-2′,4′-dinitrophenyl-3,3-dinitroazetidine (DNPDNAZ); Thermal behavior; Non-isothermal kinetics; Thermal safety
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Abstract

As N-2′,4′-dinitrophenyl-3,3-dinitroazetidine (DNPDNAZ) is an important derivative of 3,3-dinitroazetidine, its thermal behavior was studied under 0.1 and 2 MPa by the differential scanning calorimetry (DSC) method. The results of this study show that there are one melting process and two exothermic decomposition processes. Its kinetic parameters of the intense exothermic decomposition process were obtained from the analysis of the DSC curves. The activation energy and the mechanism function under 0.1 MPa are 167.26 kJ mol−1 and f(α) = 3(1 + α)2/3[(1 + α)1/3− 1]−1/2, respectively, and the said parameters under 2 MPa are 169.30 kJ mol−1 and f(α) = 3(1 + α)2/3[(1 + α)1/3− 1]−1/2, respectively. The specific heat capacity of DNPDNAZ was determined using a continuous Cp mode of micro-calorimeter. Using the relationship between Cp and T with the thermal decomposition parameters, the time of the thermal decomposition from initialization to thermal explosion (adiabatic time-to-explosion, tTIAD), the self-accelerating decomposition temperature (TSADT), thermal ignition temperature (TTIT), critical temperatures of thermal explosion (Tb), and half-life (t1/2) were obtained to evaluate its thermal safety under different pressures.

  • 1.

    Archibald, TG, Gilardi, R, Baum, K, George, C. 1990. Synthesis and X-ray crystal structure of 1,3,3-trinitroazetidine. J Org Chem. 55:2920–2924 .

  • 2.

    Hiskey, MA, Coburn, MD, Mitchell, MA, Benicewicz, BC. 1992. Synthesis of 3,3-dinitroazetidine from 1-t-butyl-3,3-dinitroazetidine. J Heterocycl Chem. 29:1855–1856 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 3.

    Hiskey, MA, Stincipher, MM, Brown, JE. 1993. Synthesis and initial characterization of some energetic salts of 3,3-dinitroazetidine. J Energy Mater. 11:157–165 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 4.

    Ma, HX, Yan, B, Li, ZN, Guan, YL, Song, JR, Xu, KZ, Hu, RZ. 2009. Preparation, non-isothermal decomposition kinetics, heat capacity and adiabatic time-to-explosion of NTO·DNAZ. J Hazard Mater. 169:1068–1073 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 5.

    Ma, HX, Yan, B, Li, ZN, Song, JR, Hu, RZ. 2009. Synthesis, molecular structure, non-isothermal decomposition kinetics and adiabatic time to explosion of 3, 3-dinitroazetidinium 3,5-dinitrosalicylate. J Therm Anal Calorim. 95:437–444 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 6.

    Ma, HX, Yan, B, Li, JF, Ren, YH, Chen, YS, Zhao, FQ, Song, JR, Hu, RZ. 2010. Molecular structure, thermal behavior and adiabatic time-to-explosion of 3,3-dinitroazetidinium picrate. J Mol Struc. 981:103–110 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 7.

    Ma, HX, Yan, B, Ren, YH, Guan, YL, Zhao, FQ, Song, JR, Hu, RZ. 2011. Thermal behavior and thermal safety on 3,3-dinitroazetidinium salt of perchloric acid. J Therm Anal Calorim. 103:569–575 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 8.

    Yan, B, Ma, HX, Hu, Y, Guan, YL, Song, JR. 2009. 1-(2,4-Dinitrophenyl)-3,3-dinitroazetidine. Acta Crystallogr E. 65:o3215 .

  • 9.

    Yan, B, Ma, HX, Li, JF, Guan, YL, Song, JR. 2010. 1-Benzoyl-3,3-dinitroazetidine. Acta Crystallogr E. 66:o57 .

  • 10.

    Ma, HX, Song, JR, Zhao, FQ, Hu, RZ, Xiao, HM. 2007. Nonisothermal reaction kinetics and computational studies on the properties of 2,4,6,8-tetranitro-2,4,6,8-tetraazabicyclo [3,3,1] onan-3,7-dione (TNPDU). J Phys Chem A. 111:8642–8649 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 11.

    Zhang, TL, Hu, RZ, Xie, Y, Li, FP. 1994. The estimation of the critical temperature of thermal explosion for energetic materials using non-isothermal DSC. Thermochim Acta. 244:171–176 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 12.

    Wang, QF, Wang, L, Zhang, XW, Mi, ZT. 2009. Thermal stability and kinetic of decomposition of nitrated HTPB. J Hazard Mater. 172:1659–1664 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 13.

    Smith, LC. 1975. An approximate solution of the adiabatic explosion problem. Thermochim Acta. 13:1–6 .

  • 14.

    Hu, RZ, Zhang, H, Xia, ZM, Guo, PJ, Gao, SL, Shi, QZ, Lu, GE, Jiang, JY. 2003. Estimation formulae of the critical rate of temperature rise for thermal explosion of exothermic decomposition reaction system of energetic materials. Chin J Energy Mater. 11:130–133 (in Chinese).

    • Search Google Scholar
    • Export Citation
  • 15.

    Zhao, HA, Hu, RZ, Wang, XJ, Zhao, FQ, Gao, HX, Zhang, H, Zhang, XL, Feng, Y, Ma, HX. 2009. Thermal safety of 1,3,3-trinitroazetidine (TNAZ). Acta Chim Sinica. 67:2536–2540 (in Chinese).

    • Search Google Scholar
    • Export Citation
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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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