Geopolymers
Inorganic polymeric new materials
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A. Czylkowska
A. Czylkowska
Institute of General and Ecological Chemistry, Technical University of Lodz, Lodz, Poland
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Abstract
Novel mixed-ligand complexes with empirical formula Ln(4-bpy)2(CCl3COO)3·nH2O [where Ln(III) = Dy, Ho, Er, Tm, Yb, Lu; 4-bpy = 4,4′-bipyridine] were prepared and characterized by chemical and elemental analysis, infrared spectroscopy, and conductivity measurements (in methanol, dimethylformamide, and dimethyl sulfoxide). X-ray powder diffraction patterns indicate that the complexes are small crystalline compounds. IR spectra of complexes show that all carboxylate groups and 4-bpy are engaged in coordination of lanthanide ions. The thermal behavior of complexes was studied by means of TG, DTG, DTA techniques in the solid state under nonisothermal conditions in air atmosphere. During heating, the complexes decompose via intermediate products to the oxide Ln2O3. The combined TG–FTIR technique was employed to study the decomposition pathway of the Ho(III) and Tm(III) complexes in flowing argon atmosphere.
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Temperature dependence of the rate of reaction in thermal analysis
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