Geopolymers
Inorganic polymeric new materials
Author:
Authors:
,
,
,
, and
Pieter Samyn
Pieter Samyn
Institute for Forest Utilization, Albert-Ludwigs-University Freiburg, Werthmannstrasse 6, 79085, Freiburg, Germany
Search for other papers by Pieter Samyn in
Current site
Google Scholar
PubMed
Search for other papers by Pieter Samyn in
Current site
Google Scholar
PubMed
Gustaaf Schoukens
Gustaaf Schoukens
Department of Textiles, Ghent University, Technologiepark 907, 9052, Zwijnaarde, Belgium
Search for other papers by Gustaaf Schoukens in
Current site
Google Scholar
PubMed
Search for other papers by Gustaaf Schoukens in
Current site
Google Scholar
PubMed
Leo Vonck
Leo Vonck
Topchim N.V, Nijverheidstraat 98, 2160, Wommelgem, Belgium
Search for other papers by Leo Vonck in
Current site
Google Scholar
PubMed
Search for other papers by Leo Vonck in
Current site
Google Scholar
PubMed
Dirk Stanssens
Dirk Stanssens
Topchim N.V, Nijverheidstraat 98, 2160, Wommelgem, Belgium
Search for other papers by Dirk Stanssens in
Current site
Google Scholar
PubMed
Search for other papers by Dirk Stanssens in
Current site
Google Scholar
PubMed
Henk Van den Abbeele
Henk Van den Abbeele
Topchim N.V, Nijverheidstraat 98, 2160, Wommelgem, Belgium
Search for other papers by Henk Van den Abbeele in
Current site
Google Scholar
PubMed
Search for other papers by Henk Van den Abbeele in
Current site
Google Scholar
PubMed
Abstract
Vegetable oils are increasingly replacing fossil-oil-based polymers, and therefore aimed at being used in polymerization reactions from −20 to 100 °C. Therefore, phase transitions and heat capacities in this temperature range should be well characterized to optimize processing conditions and energy inputs. By using the DSC analysis, only small primary correspondence or divergence between different oil types are seen as a function of their degree of unsaturation, but it does not clearly distinguish detailed features such as shoulder bands related to the separate melting processes of single fatty acid components. By using modulated DSC analysis, the combined analysis of reversing and non-reversing heat signals provides better results. The latter confirms that the melting is not a physical one-step process, but equilibrates between phase transitions and enthalpic reorganizations of the fatty acids that can be monitored separately. The specific heat capacities measured during modulated DSC are somewhat lower than traditional calorimetric measurements, but relate to the degree of unsaturation. The thermal behavior of palm-, soy-, sunflower-, corn-, castor-, and rapeseed-oil is discussed in relation to their composition, by applying a first or second heating scan.
ProCite
RefWorks
Reference Manager
BibTeX
Zotero
EndNote
-
1.
López Sastre, JA, San José Alonso, J, Romero-Ávila García, C, López Romero-Ávila, EL, Rodríguez Alonso, C. 2003. A study of the decrease in fossil CO2 emissions of energy generation by using vegetable oils as combustible. Build Environ. 38:129–133 .
-
2.
Galià, M LM de Espinosa Ronda, JC, Lligadas, G, Cádiz, V. 2010. Vegetable oil-based thermosetting polymers. Eur J Lipid Sci Technol. 112:87–96 .
-
3.
Lopes, RVV, Loureiro, NPD, Zamian, JR, Fonseca, PS, Macedo, JL, dos Santos, ML, Sales, MJA. 2009. Synthesis and characterization of polymeric materials from vegetable oils. Macromol Symp. 286:89–94 .
-
4.
Wang, C, Erhan, S. 1999. Studies of thermal polymerisation of vegetable oils with a differential scanning calorimeter. JAOCS. 76:1211–1216 .
-
5.
Santos, JCO, Dantas, JP, Medeiros, CA, Athaíde-Filho, PF, Conceiçăo, MM, Santos, JR, Souza, AG. 2005. Thermal analysis in sustainable development: thermoanalytical study of faveleira seeds (Cnidoscolus quercifolius). J Therm Anal Calorim. 79:271–275 .
-
6.
dos Reis, SCM, Lachter, ER, Nascimento, RSC, Rodrigues, JA, Reid, MG. 2005. Transesterification of Brazilian vegetable oils with methanol over ion-exchange resins. JAOCS. 82:661–665 .
-
7.
Correia IMS , Souza MJB, Araújo AS, Sousa EMBD. Thermal stability during pyrolysis of sunflower oil produced in the northeast of Brazil. J Therm Anal Calorim. 2011. doi: .
-
8.
Tavares MLA , Queiroz N, Santos IMG, Souza AL, Cavalcanti EHS. The use of DSC in evaluation of antioxidant efficiency. J Therm Anal Calorim. 2011. doi: .
-
9.
Conceição, MM VV Fernandes Jr Bezerra, AF, Silva, MCD, Santos, IMG, Silva, FC, Souza, AG. 2007. Dynamic kinetic calculation of castor oil biodiesel. J Therm Anal Calorim. 87:865–869 .
-
10.
Dantas, MB, Almeida, AAF, Conceição, MM, Fernandes, VJ, Santos, IMG, Silva, FC, Soledade, LEB, Souza, AG. 2007. Characterization and kinetic compensation effect of corn biodiesel. J Therm Anal Calorim. 87:847–851 .
-
11.
Stanssens, D H Van den Abbeele Vonck, L, Schoukens, G, Deconinck, M, Samyn, P. 2011. Creating water-repellent and superhydrophobic cellulose substrates by deposition of organic nanoparticles. Mater Lett. 65:1781–1784 .
-
12.
Dyszel, SM. 1982. A rapid screening technique for vegetable oil identity by sub-ambient DSC. Thermochim Acta. 57:209–221 .
-
13.
Nassu, RT, Goncalves, LAG. 1999. Determination of melting point of vegetable oils and fats by differential scanning calorimetry (DSC) technique. Grasas Aceitas. 50:16–22 .
-
14.
Kaisersberger, E. 1989. DSC investigations of thermal characterization of edible fats and oils. Thermochim Acta. 151:83–90 .
-
15.
Sessa, DJ, Nelson, TC, Kleiman, R, Arquette, JD. 1996. Differential scanning calorimetry index for estimation level of saturation in transesterified wax esters. JAOCS. 73:271–273 .
-
16.
Santos, JCO, Santos, MGO, Dantas, JP, Conceicao, MM, Athaide-Filho, PF, Souza, AG. 2009. Comparative study of specific heat capacities of some vegetable oils obtained by DSC and microwave oven. J Therm Anal Calorim. 79:283–287 .
-
17.
Tochitani, Y, Fujimoto, M. 2001. Measurement of specific heat capacity of vegetable oils. Netsu Bussei. 15:230–236 .
-
18.
Tan, CP, Che Man, YB. 2000. Differential scanning calorimetric analysis of edible oils: comparison of thermal properties and chemical composition. JAOCS. 77:143–155 .
-
19.
Salimon, J, Abdullah, BM. 2009. A study on the thermal properties and solid fat content of Malaysian rubber seed oil. Malays J Anal Sci. 13:1–7.
-
20.
Kowalski, B. 1990. Determination of spontaneous ignition temperatures of edible oils and fats by pressure differential scanning calorimetry. Thermochima Acta. 173:117–127 .
-
21.
Dian, NLH, Sundral, K, Idris, NA. 2006. DSC study on the melting properties of palm oil, sunflower oil, and palm kernel olein blends before and after chemical interesterification. JAOCS. 83:739–745 .
-
22.
Siew, WL. 2001. Crystallisation and melting behaviour of palm kernel oil and related products by differential scanning calorimetry. Eur J Lipid Sci Technol. 103:729–734 .
-
23.
Kawamura, K. 1981. The DSC thermal analysis of crystallization behaviour in high erucic acid rapeseed oil. JAOCS. 8:826–829.
-
24.
Zhang, L, Muramoto, H, Ueno, S, Sato, K. 2011. Crystallisation of fully hydrogenated and interesterified fat and vegetable oil. J Oleo Sci. 60:287–292 .
-
25.
Tan, CP, Che Man, YB. 1999. Quantitative differential scanning calorimetric analysis for determining total polar compounds in heated oils. JAOCS. 9:1047–1057.
-
26.
Danthine, SB, Gibon, V, Deroanne, C. 2005. Physicochemical characteristics of ternary fat blends involving low-erucic rapeseed oil. Eur J Lipid Sci Technol. 107:627–633 .
-
27.
Siddique, BM, Ahmad, A, Ibrahim, MH, Hena, S, Rafatullah, M, Omar, M. 2010. Physico-chemical properties of blends of palm olein with other vegetable oils. Grasas Aceites. 61:423–429 .
-
28.
AG de Sousa Santos, JCO, Conceicao, MM, Silva, MC, Prasad, S. 2004. A thermoanalytical and kinetic study of sunflower oil. Braz J Chem Eng. 21:265–273 .
-
29.
Nzikou, JM, Matos, L, Moussounga, JE, Ndangiu, CB, Pambou-Tobi, NP, Bandzouzi, EM, Kimbonguila, A, Linder, M, Desobry, S. 2009. Study of oxidative and thermal stability of vegetable oils during frying. Res J Appl Sci. 4:94–100.
-
30.
Azis, A, Mohamud, Y, Roselina, K, Boo, HC, Nyuk, L, Che Man, YB. 2011. Rheological, chemical and DSC thermal characteristics of different types of palm oil/palm stearing-based shortenings. Int Food Res J. 18:189–200.
-
31.
Abdulkarim, SM, Ghazali, HM. 2007. Comparison of melting behaviours of edible oils using conventional and hyper differential scanning calorimetric scan rates. ASEAN Food J. 14:25–35.
-
32.
Tan, CP, Che Man, YB. 2002. Comparative differential scanning calorimetric analysis of vegetable oils: I. Effects of heating rate variation. Phytochem Anal. 13:129–141 .
-
33.
Kanavouras, A, Selke, S. 2004. Evolution of thermograph parameters during the oxidation of extra virgin olive oil. Eur J Lipid Sci Technol. 106:359–368 .
-
34.
Samyn P , Van Nieuwkerke D, Schoukens G, Vonck L, Stanssens D, Van den Abbeele H. Quality and statistical quantification of Brazilian vegetable oils using FTIR and Raman spectroscopy. Appl Spectrosc. 2011.
-
35.
Carneiro, PIB, Reda, SY, Carneiro, EBB. 2005. H-NMR characterization of seed oils from Rangpur lime and Sicilian lemon. Ann Magn Reson. 4:64–68.
-
36.
FR Van de Voort Ismail, AA, Sedman, J, Dubois, J, Nicodemo, T. 1994. The determination of peroxide value by Fourier transform infrared spectroscopy. JAOCS. 71:921–926 .
-
37.
Che Man, YB, Mirghani, MES. 2000. Rapid method for determining moisture content in crude palm oil by Fourier transform infrared spectroscopy. JAOCS. 77:631–637 .
-
38.
Deman, JM, Deman, L, Blackman, B. 1983. Melting-point determination of fat products. JAOCS. 60:15–18.
-
39.
Che Man, YB, Haryati, GT, Asbi, BA. 1999. Composition and thermal profile of crude palm oil and its products. JAOCS. 76:215–220 .
-
40.
Jacobsberg, B, Ho, OC. 1976. Studies in palm oil crystallization. JAOCS. 71:609–617.
-
41.
Czerniak, SA, Karlovits, G, Lach, M, Szyk, E. 2005. X-ray diffraction and differential thermal scanning calorimetry studies of transitions in fat mixtures. Food Chem. 92:133–141 .
-
42.
Chiavarro, E, Vittadini, E, Rodriguez-Estrada, MT, Cerretani, L, Bendini, A. 2008. Differential scanning calorimeter application to the detection of refined hazelnut oil in extra virgin olive oil. Food Chem. 110:248–256 .
-
43.
Chen, CW, Chong, CL, Ghazali, HM, Lai, OM. 2007. Interpretation of triacylglycerol profiles of palm oil, palm kernel oil and their binary blends. Food Chem. 100:178–191 .
-
44.
Masson, JF, Polomark, GM, Collins, P. 2002. Time-dependent microstructure of bitumen and its fractions by modulated differential scanning calorimetry. Energy Fuel. 16:470–476 .
-
45.
Wunderlich, B, Okazaki, I, Ishikiriyama, K, Boller, A. 1998. Melting by temperature-modulated calorimetry. Thermochim Acta. 324:77–85 .
-
46.
Che Man, YB, Swe, PZ. 1995. Thermal analysis of failed-batch palm oil by differential scanning calorimetry. JAOCS. 72:1529–1532 .
-
47.
Siew, WL, Ong, ASH, Oh, FCH, Berger, KG. 1982. Critical aspects of slip melting point measurements. PORIM Bull. 4:1–18.
-
48.
Morad, NA, Kamal, AAM, Panau, F, Yew, TW. 2000. Liquid specific heat capacity estimation for fatty acids, triacylglycerols and vegetable oils based on their fatty acid composition. JAOCS. 77:1001–1005 .
-
49.
Choi, Y, Okos, MR. 1986. Food engineering and process applications, vol 1 P Jelen M Le Maguer eds. Transport phenomena Elsevier Applied Science London 93–101.
-
50.
Heidenreich, S, Langner, T, Rohm, H. 2007. Heat capacity of cheese. J Therm Anal Calorim. 89:815–819 .
-
51.
Fasina, OO, Colley, Z. 2008. Viscosity and specific heat of vegetable oils as a function of temperature: 35°C to 180°C. Int J Food Prop. 11:738–746 .
-
52.
Rodenbush, CM, Hsieh, FH, Viswanath, DS. 1999. Density and viscosity of vegetable oils. JAOCS. 76:1415–1419 .
To see the editorial board, please visit the website of Springer Nature.
Manuscript Submission: HERE
For subscription options, please visit the website of Springer Nature.
| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
Monthly Content Usage
| Abstract Views | Full Text Views | PDF Downloads | |
|---|---|---|---|
| Jun 2024 | 28 | 0 | 0 |
| Jul 2024 | 44 | 0 | 0 |
| Aug 2024 | 21 | 0 | 0 |
| Sep 2024 | 87 | 0 | 0 |
| Oct 2024 | 231 | 0 | 0 |
| Nov 2024 | 91 | 0 | 0 |
| Dec 2024 | 15 | 0 | 0 |
Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
Author:
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Powered by PubFactory