Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 110: Issue 3
Thermochemical properties of di(N,N-di(2,4,6-trinitrophenyl)amino)-ethylenediamine in dimethyl sulfoxide and N-methyl pyrrolidone
Authors:
Li Bai Xiao Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Xiao Ling Xing Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Xue Zhong Fan Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Feng Qi Zhao Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Zhi Ming Zhou School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China

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Hai Feng Huang School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China

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Ting An Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Hai Xia Hao Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Qing Pei Science and Technology on Combustion and Explosion Laboratory, Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

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Pages:
1431–1436
Online Publication Date:
07 Dec 2011
Publication Date:
01 Dec 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s10973-011-2036-1
Keywords:
Di(N,N-di(2,4,6-trinitrophenyl)amino)-ethylenediamine; Dimethyl sulfoxide; Kinetics; N-methyl pyrrolidone; Dissolution
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Abstract

The enthalpies of dissolution for di(N,N-di(2,4,6,-trinitrophenyl)amino)-ethylenediamine (DTAED) in dimethyl sulfoxide (DMSO) and N-methyl pyrrolidone (NMP) were measured using a RD496-2000 Calvet microcalorimeter at 298.15 K. Empirical formulae for the calculation of the enthalpies of dissolution (ΔdissH) were obtained from the experimental data of the dissolution processes of DTAED in DMSO and NMP. The linear relationships between the rate (k) and the amount of substance (a) were found. The corresponding kinetic equations describing the two dissolution processes were for the dissolution of DTAED in DMSO, and for the dissolution of DTAED in NMP, respectively.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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