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  • 1 Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, F. Engels’ pr., 7, Ivanovo, Russia
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Abstract

The calorimetric method was used to determine the heats of glycine-ion (Gly) protonation and silver(I) glycine-ion complexation at the ionic strength 0.3 (NaClO4) and 298 K in the range of mixed solvent composition of 0.0 < χ < 0.3 and 0.0 < χ <0.4 molar fraction of dimethylsulfoxide, respectively. Anomalous ratio of enthalpies change of step formation of mono-glycinate and bis-glycinate complexes in water was revealed. The exothermicity of second ligand joining is almost twice the coordination effect of the first one. It was shown the decrease of glycine-ion solvation is the main reason of enthalpies change in case of glycine-ion protonation and silver(I) glycine-ion complexation in aqueous-dimethylsulfoxide solutions.

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  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
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  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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