Geopolymers
Inorganic polymeric new materials
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Gaochao Fan
Gaochao Fan
College of Chemistry & Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China
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Zaiyin Huang
Zaiyin Huang
College of Chemistry & Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China
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Junying Jiang
Junying Jiang
College of Chemistry & Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China
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Li Sun
Li Sun
College of Chemistry & Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, People's Republic of China
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Abstract
ZnO nanosheets were prepared by a facile microemulsion-mediated hydrothermal route, and were characterized by X-ray powder diffraction, field-emission scanning electron microscopy, and transmission electron microscopy. As nano ZnO and bulk ZnO possess the same reaction essence, the relationship between standard molar enthalpies of formation of nano ZnO and bulk ZnO was built by designing a novel thermochemical cycle. Combined with microcalorimetry, standard molar enthalpy of formation of the as-prepared ZnO nanosheets at 298.15 K was successfully acquired as (−333.50 ± 0.29) kJ mol−1. It is an effective strategy for standard molar enthalpies of formation of nano materials through building the relationship with its corresponding bulk material.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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