Authors:
B. V. Slobodin Institute of Chemistry Uralian Scientific Centre of the Academy of the U. S. S. R. Sverdlovsk U S S R

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V. A. Zhilaev Institute of Chemistry Uralian Scientific Centre of the Academy of the U. S. S. R. Sverdlovsk U S S R

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A. A. Fotiev Institute of Chemistry Uralian Scientific Centre of the Academy of the U. S. S. R. Sverdlovsk U S S R

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I. A. Arapova Institute of Chemistry Uralian Scientific Centre of the Academy of the U. S. S. R. Sverdlovsk U S S R

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N. P. Tugova Institute of Chemistry Uralian Scientific Centre of the Academy of the U. S. S. R. Sverdlovsk U S S R

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The interaction of V2O5 with calcium oxide and calcium carbonate was studied by thermal analysis. The results indicated that the macrosuccession of the phase transformations in the systems CaO-V2O5 and CaCO3-V2O5 corresponds to an increasing calcium content in each successively formed calcium vanadate. Thermodynamical calculations carried out by methods available in the literature for determining the primary products and the succession of the subsequently formed products demonstrate that chemical reactions proceeding in the above systems are controlled by kinetic and not by thermodynamic factors.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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