Gh. Drăgan Institute of Chemical Research ICECHIM Spl. Independentei 202 77208 Bucharest Romania

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The relationship between the behaviour of a composite system and the boundary conditions imposed by the external energetic circuit from a laboratory reference system is established. The thermally activated character of the transformation processes visualized in the measuring systems is expressed topologically by superposition of the time and temperature dependences (of Arrhenius type) for the component which is found in transformation relative to the laboratory system. The temporal relativistic principle is extended to the thermally driven processes by using this superposition condition. The kinetic equations for three particular cases of purely dissipative coupling are deduced in this way: in the case when the two fluxes associated with the component are of opposite directions; the shift equation for the relaxation periods in amorphous morphology; and for the case of capacitive dependence as boundary condition.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
per Year
per Year
Founder Akadémiai Kiadó
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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