Authors:
E. Paterson Department of Pedology The Macaulay Institute for Soil Research AB9 2QJ Craigiebuckler Aberdeen Scotland

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R. Swaffield Department of Pedology The Macaulay Institute for Soil Research AB9 2QJ Craigiebuckler Aberdeen Scotland

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The influence of surface structure on the dehydroxylation of synthetic goethite has been studied using heat-flux differential scanning calorimetry. Adsorption of various anions by goethite causes a progressive change in both the amount and environment of surface hydroxyls and this is reflected by changes in the DSC curves. These alterations indicate the importance of surface features in determining the course of dehydroxylation and further suggest that, in studies of this type of reaction, the use of synthetic products known to be free of surface contaminants could prove to be of great value in understanding dehydroxylation mechanisms.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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