Author:
S. U. Sheikh Department of Chemistry Quaid-i-Azam University Islamabad Pakistan

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Thermal decompositions of tetraalkylammonium haloborates, R4N+BX4 (whereR=Et orn-Bu, andX=Cl, Br or PhBCl2), have been studied by both bench pyrolysis and thermoanalytical techniques. The first stage in the thermal decomposition of the haloborates involves the loss of one mole of an alkyl halide with the formation of a 1∶1 complex. Thermal decomposition of the haloborates beyond the stage of formation of haloboranes leads to the evolution of further quantities of alkyl halides together with the corresponding boron trihalide. In many instances the final products were polymeric materials of the general type:.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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