Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 21: Issue 2
Cyclophane bis(sulfoxides) a thermal analysis study
Authors:
J. O. Hill Department of Chemistry La Trobe University 3083 Bundoora Victoria Australia

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P. J. Jessup Department of Chemistry La Trobe University 3083 Bundoora Victoria Australia

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J. A. Reiss Department of Chemistry La Trobe University 3083 Bundoora Victoria Australia

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Pages:
271–276
Online Publication Date:
25 Jul 2005
Publication Date:
01 Aug 1981
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01914210
Restricted access

A thermogravimetry study of a series of cyclophane bis(sulfoxides) (1–6) has shown that thermal decomposition of these compounds occurs in two stages with a stepwise loss of the sulfoxide groups at well defined decomposition temperatures. The stepwise thermal cleavage has been rationalized in terms of the stereochemistry of the sulfoxide groups and the strain associated with the resultant elimination products.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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