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The thermal decomposition behaviour of copper oxalate hemihydrate and its complexes with different amines has been studied by TG and DTA methods in nitrogen and air atmospheres. The complexes CuC2O4 · 0.5 H2O, CuC2O4(NH3)2 and CuC2O4(py) produced Cu2O as final residue after decomposition, whereas, another group of complexes, CuC2O4(EtNH2)2, CuC2O4(MeNH2)2, CuC2O4(en)2 and CuC2O4(An)2, gave a final residue of CuO. All the complexes decomposed without forming any isolable stable intermediate; an exception was CuC2O4(en)2, which formed a binuclear intermediate complex, [CuC2O4en]2.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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