Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 27: Issue 2
Thermal behaviour of copper oxalate and its mixed ligand complexes with amines
Authors:
P. C. Srivastava Projects and Development India Ltd. 929122 Sindri India

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B. N. Singh Projects and Development India Ltd. 929122 Sindri India

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S. D. Adhya Projects and Development India Ltd. 929122 Sindri India

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K. C. Banerji Projects and Development India Ltd. 929122 Sindri India

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Pages:
263–273
Online Publication Date:
01 Aug 2005
Publication Date:
01 Jul 1983
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01914662
Restricted access

The thermal decomposition behaviour of copper oxalate hemihydrate and its complexes with different amines has been studied by TG and DTA methods in nitrogen and air atmospheres. The complexes CuC2O4 · 0.5 H2O, CuC2O4(NH3)2 and CuC2O4(py) produced Cu2O as final residue after decomposition, whereas, another group of complexes, CuC2O4(EtNH2)2, CuC2O4(MeNH2)2, CuC2O4(en)2 and CuC2O4(An)2, gave a final residue of CuO. All the complexes decomposed without forming any isolable stable intermediate; an exception was CuC2O4(en)2, which formed a binuclear intermediate complex, [CuC2O4en]2.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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