Authors:
S. Otin Departamento de Quimica Fisica, Faultad de Ciencias Universidad de Zaragoza Spain

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J. M. Lozano Departamento de Quimica Fisica, Faultad de Ciencias Universidad de Zaragoza Spain

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C. Gutierrez Losa Departamento de Quimica Fisica, Faultad de Ciencias Universidad de Zaragoza Spain

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Excess molar enthalpies,HE, at atmospheric pressure and 303.15 K are reported for binary mixtures of 1-chlorohexane with diethyl oxalate, diethyl malonate, diethyl succinate, diethyl glutarate, diethyl adipate, diethyl pimelate and diethyl sebacate. These experimental results, together with those obtained previously on the excess enthalpies of aliphatic diester+n-hexane mixtures, are interpreted in terms of molecular surface interactions between aliphatic, chlorinated and carboxylate groups. Comparison of the enthalpy interchange parameters reveals a decrease of the intermolecular interactions with decreasing intramolecular COO-COO distance in the diester molecule.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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