Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 31: Issue 2
Thermal decomposition of dicitratoborates
Authors:
E. M. Schwartz

Search for other papers by E. M. Schwartz in
Current site
Google Scholar
PubMed Close
,
I. M. Vitola

Search for other papers by I. M. Vitola in
Current site
Google Scholar
PubMed Close
,
G. S. Sergeiyeva

Search for other papers by G. S. Sergeiyeva in
Current site
Google Scholar
PubMed Close
,
G. O. Piloyan

Search for other papers by G. O. Piloyan in
Current site
Google Scholar
PubMed Close
, and
O. V. Drozdova

Search for other papers by O. V. Drozdova in
Current site
Google Scholar
PubMed Close
Pages:
351–359
Online Publication Date:
25 Jul 2005
Publication Date:
01 Mar 1986
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01911067
Restricted access

The thermal decompositions of dicitratoborates M1[B(C6H6O7)2]·nH2O (n=0–2, M1=Rb, K, Li, NH4) and M11[B(C6H6O7)2]2·8H2O (M11=Co, Ni, Mn, Cu, Zn, Cd) were investigated by means of TG, DTA and DTG methods. It was found that these thermal decompositions involve three successive stages: dehydration, the endothermal decomposition of the ligand, and oxidation of the residual organic component. The volatile products of decomposition in each stage were detected by means of gas chromatography. The method of TG-curve transformation into the curvedm/d T vs.m, wherem is the loss of weight at each moment of time, was used for a more detailed study of dehydration. The optimal conditions for TG-curve modification were found.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2024 2 0 0
May 2024 1 0 0
Jun 2024 3 0 0
Jul 2024 7 0 0
Aug 2024 14 0 0
Sep 2024 8 0 0
Oct 2024 1 0 0