Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 32: Issue 4
Thermal decomposition kinetics of Schiff base complexes of copper(II) and palladium(II)
Authors:
V. Indira Department of Chemistry University of Calicut 673 635 India

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G. Parameswaran Department of Chemistry University of Calicut 673 635 India

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Pages:
1151–1162
Online Publication Date:
22 Jul 2005
Publication Date:
01 Jul 1987
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01905170
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Thermogravimetric (TG), derivative thermogravimetric (DTG) and differential thermal analysis (DTA) curves of CuL2 and Pd(LH)2Cl2 (LH=salicylidene-2-aminofluorene and 2-hydroxy-1-naphthalidene-2-aminofluorene) in air are studied. Mass loss considerations at the main decomposition stages indicate conversion of the complex to oxides. Mathematical analysis of TG data shows that first order kinetics are applicable in all cases. Kinetic parameters (energy and entropy of activation and preexponential factor) are reported.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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