Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 32: Issue 4
The importance of the CO22−anion in the mechanism of thermal decomposition of oxalates
Authors:
A. Górski Institute of Basic Chemistry, Department of Chemistry Warsaw Technical University Warsaw Poland

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A. D. Kraśnicka Institute of Basic Chemistry, Department of Chemistry Warsaw Technical University Warsaw Poland

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Pages:
1229–1241
Online Publication Date:
22 Jul 2005
Publication Date:
01 Jul 1987
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01905177
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The effects of active (carbon dioxide and carbon monoxide) and neutral (helium, argon and nitrogen) atmospheres on the course of thermal decomposition of oxalates have been studied and compared. A mechanism of thermal decomposition has been proposed on the basis of the results obtained, the first stage of which consists in a heterolytic dissociation of the C-C bond, with the formation of carbon dioxide and the CO22−anion.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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