Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 32: Issue 4
Kinetic analysis of the liquid-phase depolymerization of trioxane from programmed-temperature data
I. Integral kinetic analysis
Authors:
M. I. Ortiz Dpto. de Quimica Técnica, Facultad de Ciencias Universidad del Pais Vasco Apdo. 644 Bilbao Spain

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A. Irabien Dpto. de Quimica Técnica, Facultad de Ciencias Universidad del Pais Vasco Apdo. 644 Bilbao Spain

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Pages:
997–1004
Online Publication Date:
22 Jul 2005
Publication Date:
01 Jul 1987
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01905155
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An experimental method for the determination of kinetic data for liquid-phase reactions under linear rise of temperature is explained for the depolymerization of trioxane. Integral kinetic analysis of the data is performed in order to determine the kinetic model and the kinetic parameters. Experiments have been carried out at different heating rates between 0.5 and 2 deg/min, leading to similar kinetic parameters. The obtained results are in agreement with the kinetic model and parameters obtained from isothermal kinetic analysis. The programmedtemperature method seems to be a useful tool for a quick determination of kinetic models, avoiding experimental work.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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