The interrelations between the correlation coefficients (=r) for an Arrhenius representation (linearity lnk vs. 1/T) of runs evaluated by the one-step strategy, and their locations in the mechanistic diagram (reaction type indexM vs. shape indexS) are studied, based on 3000 DTA and UV experiments and 850 theoretical curves for 40 reaction mechanisms. It turns out that files corresponding to the source points of first- or second-order, or to theA-region located between, reveal a reliable Arrhenius line; but for particular mechanisms, files attributable to regions rather “distant” from this center, may also behave so. Therefore, further studies must lead to powerfulr,S,M-based kinetic pattern recognition methods.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
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