Author: E. Koch 1
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  • 1 Max-Planck-Institut für Strahlenchemie Stiftstr 34-36 Mülheim A. D. Ruhr Germany
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The interrelations between the correlation coefficients (=r) for an Arrhenius representation (linearity lnk vs. 1/T) of runs evaluated by the one-step strategy, and their locations in the mechanistic diagram (reaction type indexM vs. shape indexS) are studied, based on 3000 DTA and UV experiments and 850 theoretical curves for 40 reaction mechanisms. It turns out that files corresponding to the source points of first- or second-order, or to theA-region located between, reveal a reliable Arrhenius line; but for particular mechanisms, files attributable to regions rather “distant” from this center, may also behave so. Therefore, further studies must lead to powerfulr,S,M-based kinetic pattern recognition methods.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
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Founder Akadémiai Kiadó
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Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
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CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)