Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 33: Issue 1
Proof of the kinetic reaction mechanism of PVC degradation using TA
Authors:
J. Behnisch Institut fuer Polymerenchemie ‘Erich Correns’ der ADW der DDR 1530 Teltow Germany

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H. Zimmermann Institut fuer Polymerenchemie ‘Erich Correns’ der ADW der DDR 1530 Teltow Germany

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Pages:
191–196
Online Publication Date:
25 Jul 2005
Publication Date:
01 Mar 1988
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01914599
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The possibility of describing the kinetics of thermal degradation of PVC samples under both isothermal and nonisothermal conditions with a unique model and using the same set of parameters was investigated. Analysis of the experimental data revealed good agreement at higher temperatures (above 175 °C) when the catalytic action of generated HCl and its distribution in the sample were considered. At lower reaction temperatures, further experimental conditions and/or sample characteristics must be considered, and a modification of the model is necessary.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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