Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 33: Issue 1
Influence of the sample mass and the presence of the reaction products on the thermoanalytical results
Authors:
G. VárhegyiResearch Laboratory for Inorganic Chemistry Hungarian Academy of Sciences P.O.Box 132 1502 Budapest Hungary

Search for other papers by G. Várhegyi in
Current site
Google Scholar
PubMedClose
,
T. SzékelyResearch Laboratory for Inorganic Chemistry Hungarian Academy of Sciences P.O.Box 132 1502 Budapest Hungary

Search for other papers by T. Székely in
Current site
Google Scholar
PubMedClose
,
F. TillResearch Laboratory for Inorganic Chemistry Hungarian Academy of Sciences P.O.Box 132 1502 Budapest Hungary

Search for other papers by F. Till in
Current site
Google Scholar
PubMedClose
,
E. JakabResearch Laboratory for Inorganic Chemistry Hungarian Academy of Sciences P.O.Box 132 1502 Budapest Hungary

Search for other papers by E. Jakab in
Current site
Google Scholar
PubMedClose
, and
P. SzabóResearch Laboratory for Inorganic Chemistry Hungarian Academy of Sciences P.O.Box 132 1502 Budapest Hungary

Search for other papers by P. Szabó in
Current site
Google Scholar
PubMedClose
View More View Less
Pages:
87–95
Online Publication Date:
25 Jul 2005
Publication Date:
01 Mar 1988
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01914587
Restricted access

It has been known from the very beginning of the thermal analysis that the transport processes can significantly influence the thermoanalytical results. In this paper, three characteristic examples are given to show that this problem is more complex and arises more frequently than it is generally believed. The studied reactions are the carbon monoxide evolution from calcium oxalate, the thermal degradation of polytetrafluoroethylene, and the thermal decomposition of azodicarbonamide. TG and DSC experiments were carried out with sample masses varying between 0.05 and 8 mg. The necessity of the development of new kinetic models is concluded.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Oct 2022 1 0 0
Nov 2022 0 0 0
Dec 2022 0 0 0
Jan 2023 0 0 0
Feb 2023 0 0 0
Mar 2023 0 0 0
Apr 2023 0 0 0