Authors:
I. Horváth
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I. Bondar Academy of Sciences of the USSR Institute of Silicate Chemistry 199 164 Leningrad USSR

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L. Mezentseva Academy of Sciences of the USSR Institute of Silicate Chemistry 199 164 Leningrad USSR

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The hydrated rare earth orthophosphates LnPO4 ·xH2O (Ln=La-Dy) contain zeolitic water in the structural channels, which is released reversibly up to 300°. The thermal stabilities of the hydrates depend upon the nature of the Ln atom. The dehydration temperature decreases with decreasing ionic radiusr of Ln3+, according to the general equationθ=(r−a)/b (whereθ is the DSC and/or DTG dehydration peak temperature, anda andb are empirical constants depending on the experimental conditions).

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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