Authors:
W. Brzyska Department of Inorganic and General Chemistry, Institute of Chemistry Marie Curie Skłodowska University 20-031 Lublin Poland

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M. Hakim Department of Inorganic and General Chemistry, Institute of Chemistry Marie Curie Skłodowska University 20-031 Lublin Poland

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The conditions of thermal decomposition of the hippurates of Y, La and the light lanthanides from Ce(III) to Gd have been studied. When heated, the Y, Ce(III), Pr and Gd complexes decomposed in two stages, those of La, Sm and Eu in three stages, and that of Nd in four stages, the oxides finally being formed. The complexes lost crystallization water to form anhydrous (Nd) or hydrated salts, and then decomposed to oxides directly (Y, Ce(III), Pr(III) and Gd) or with intermediate formation of Ln2O2CO3 (La, Nd, Sm and Eu). The temperature of oxide formation varied periodically with the ionic potential in the lanthanide series.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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