Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 34: Issue 4
Thermal properties of solid nickel(II) coordination compounds Part B: Thermal octahedral ↔ square planar transformations
Author:
E. JónaDepartment of Inorganic Chemistry Slovak Technical University 812 37 Bratislava Czechoslovakia

Search for other papers by E. Jóna in
Current site
Google Scholar
PubMedClose
View More View Less
Pages:
1053–1072
Online Publication Date:
25 Jul 2005
Publication Date:
01 Jul 1988
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01913510
Restricted access

The paper deals with the chemical and physical factors influencing the thermal octahedral ↔ square planar changes of nickel(II) complexes in the solid phase. The relationship between these transformations and the tetragonal distortion of the octahedral ligand field is discussed. Depending on the coordination of the ligands, these transformations can be divided into two groups: octahedral monomer ↔ square planar monomer, and octahedral polymer ↔ square planar monomer changes. Attention is directed only to octahedral and square planat Ni(II) complexes (square planar complexes with chromophores [NiN4], [NiN2O2] and [NiO4]), which can be isolated in the solid state before and after heating. The possibility of such a configurational change seems to be dependent upon the thermal stabilities of the initial and final complexes, the electronic and steric properties of the ligands, the complexing ability of the central atom, and particularly the equatorial-axial interactions of the ligands via the central atom.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Oct 2022 1 0 0
Nov 2022 0 0 0
Dec 2022 0 0 1
Jan 2023 1 0 0
Feb 2023 0 0 0
Mar 2023 1 0 0
Apr 2023 0 0 0