Author:
S. R. YoganarasimhanIDL-Nitro Nobel Basic Research Institute Sankey Road P.B. No. 397 560 003 Malleswaram, Bangalore India

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The acceleratory effect of potassium perchlorate on the reactivity of the red lead-silicon system has been studied by employing DTA and DSC. Supporting investigations on pure potassium perchlorate and the binary system red lead-potassium perchlorate suggest that the complex decomposition kinetics of potassium perchlorate drastically influences the oxidation of silicon. Further, the ternary system also undergoes a transition from exothermic smooth decomposition to ignition at a certain critical mass, as noted in the red lead-silicon and iron(III) oxide system. The criticality should be a result of the rise in temperature expressed as a perturbation of the steady-state energy conservation conditions, as postulated by Gray.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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