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  • 1 Department of Inorganic Chemistry University of Murcia Murcia Spain
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The 1 ∶ 4 complexes of cobalt (II) and manganese (II) thiocyanates with morpholine (Morph), [M(NCS)2(Morph)4] (M=Co, Mn), were prepared and studied by means of thermogravimetry, derivative thermogravimetry and differential scanning calorimetry. By thermal treatment of the above compounds, the 1∶2 and 1∶1 complexes, [M(NCS)2(Morph)2] (M=Co, Mn; n=1, 2), were formed. Magnetic data, infrared and electronic spectra and molar conductance values for the compounds are reported. All the complexes contain N-bonded morpholine and the 1∶4 complexes are suggested to have a monomericcis pseudooctahedral structure with N-bonded thiocyanate, whereas the 1∶2 and 1∶1 complexes are considered to have a six-coordinated polymeric configuration involving bridging NCS groups.

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  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
per Year
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Founder Akadémiai Kiadó
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)